Investigation of the hydrogen interaction with Ti0.9Zr0.1Mn1.3V0.7 by means of the calorimetric method

被引:7
|
作者
Anikina, E. Yu. [1 ]
Verbetsky, V. N. [1 ]
机构
[1] Lomonosou Moscow State Univ, Chem Dept Moscow, Moscow 119991, Russia
关键词
Intermetallic compound; Hydride; Ti0.9Zr0.1Mn1.3V0.7-H-2; system; Calorimetry;
D O I
10.1016/j.ijhydene.2015.12.126
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present work we studied the hydrogen interaction with the stoichiometric Ti0.9Zr0.1Mn1.3V0.7 Laves phase compound C14 at pressure up to 50 atm and the temperature range from 52 to 130 degrees C by means of calorimetric method and plotting of pressure composition isotherms. The processes of hydrogen absorption and desorption were carried out. The findings enabled us to draw the following conclusions: 1) the experimental temperature influences the thermodynamic parameters of studied processes and 2) depending on reaction conditions the formation of one or two hydride phases takes place. (C) 2015 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:11520 / 11525
页数:6
相关论文
共 50 条
  • [42] Mechanism of hydrogen absorption in Zr0.9Ti0.1Ni1.1Co0.1Mn0.6V0.2 alloy during alkali treatment with a boiling 6 M KOH solution
    Iwakura, C
    Choi, WK
    Zhang, SG
    Inoue, H
    ELECTROCHIMICA ACTA, 1999, 44 (10) : 1677 - 1679
  • [43] Microstructure and high-temperature electrochemical characteristics of Zr0.9Ti0.1Ni1.0Mn0.7V0.3Six (x=0.05, 0.10, 0.15, 0.20) alloy
    Han, SM
    Zhao, MS
    Liu, AZ
    MATERIALS CHEMISTRY AND PHYSICS, 2005, 89 (2-3) : 221 - 227
  • [44] Comprehensive hydrogen storage properties of free-V Ti 1- x Zr x Mn 0.9 Cr 0 . 7 Fe 0.1 alloys with different Zr substitution content
    He, Binbin
    Lu, Yanshan
    Jiang, Jun
    Zhan, Zhilin
    Ni, Baojia
    Lv, Lijun
    Pan, Taijun
    PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2024, 34 (05) : 977 - 984
  • [45] Dielectric characteristics investigation of (Ba0.7Sr0.3)(Ti0.9Zr0.1)O3 ferroelectric thin films
    Chen, Kai-Huang
    Wu, Sean
    Huang, Shou-Jen
    INTEGRATED FERROELECTRICS, 2016, 168 (01) : 18 - 24
  • [47] Fe0.85Mn0.15Ti0.9M0.1(M=Zr,V,Ca)合金的贮氢性能
    马建新
    潘洪革
    李寿权
    王新华
    陈长聘
    稀有金属材料与工程, 2000, (02) : 137 - 140
  • [48] Study on the structure and electrochemical properties of melt-spun Zr0.9Ti0.1(Ni,Co,Mn,V)2.1 alloys
    Wen, MG
    Song, CL
    Chen, L
    Zhai, YC
    JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (08) : 2543 - 2545
  • [49] EffectofdifferentmetalelementsubstitutiononmicrostructuralandcomprehensivehydrogenstorageperformanceofTi0.9Zr0.1Mn0.95Cr0.7V0.2M0.15(M=Fe,Co,Ni,Cu,Mo)alloy
    Baojia Ni
    Jianhui Zhu
    Guo Yang
    Linhua Xu
    Haiyan Leng
    Wei Liu
    Taijun Pan
    Xingbo Han
    Lijun Lv
    ProgressinNaturalScience:MaterialsInternational, 2024, 34 (02) : 304 - 313
  • [50] Electrical characterization of Mn doped-(Ba0.3Sr0.7)Mnx(Ti0.9Zr0.1)1-xO3 ceramics
    Mahmood, A.
    Naeem, A.
    Iqbal, Y.
    Mahmood, T.
    Ullah, A.
    MATERIALS RESEARCH BULLETIN, 2015, 72 : 13 - 19