In the present work we studied the hydrogen interaction with the stoichiometric Ti0.9Zr0.1Mn1.3V0.7 Laves phase compound C14 at pressure up to 50 atm and the temperature range from 52 to 130 degrees C by means of calorimetric method and plotting of pressure composition isotherms. The processes of hydrogen absorption and desorption were carried out. The findings enabled us to draw the following conclusions: 1) the experimental temperature influences the thermodynamic parameters of studied processes and 2) depending on reaction conditions the formation of one or two hydride phases takes place. (C) 2015 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
机构:
Guangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R ChinaGuangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R China
He, Binbin
Lu, Yanshan
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Guangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R ChinaGuangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R China
Lu, Yanshan
Jiang, Jun
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Guangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R ChinaGuangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R China
Jiang, Jun
Zhan, Zhilin
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Guangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R ChinaGuangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R China
Zhan, Zhilin
Ni, Baojia
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Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
Changzhou Univ, Sch Mat Sci & Engn, Changzhou 213164, Peoples R ChinaGuangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R China
Ni, Baojia
Lv, Lijun
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Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R ChinaGuangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R China
Lv, Lijun
Pan, Taijun
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Changzhou Univ, Sch Mat Sci & Engn, Changzhou 213164, Peoples R ChinaGuangdong Power Grid Co Ltd, Guangzhou Power Supply Bur, Guangzhou 510620, Peoples R China
机构:
School of Materials Science and Engineering, Changzhou University
Shanghai Institute of Applied Physics, Chinese Academy of SciencesSchool of Materials Science and Engineering, Changzhou University
Baojia Ni
Jianhui Zhu
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Shanghai Institute of Applied Physics, Chinese Academy of Sciences
School of Materials Science and Engineering, ShanghaiSchool of Materials Science and Engineering, Changzhou University
Jianhui Zhu
Guo Yang
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Shanghai Institute of Applied Physics, Chinese Academy of SciencesSchool of Materials Science and Engineering, Changzhou University
Guo Yang
Linhua Xu
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Shanghai Institute of Applied Physics, Chinese Academy of SciencesSchool of Materials Science and Engineering, Changzhou University
Linhua Xu
Haiyan Leng
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机构:
School of Materials Science and Engineering, ShanghaiSchool of Materials Science and Engineering, Changzhou University
Haiyan Leng
Wei Liu
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Shanghai Institute of Applied Physics, Chinese Academy of SciencesSchool of Materials Science and Engineering, Changzhou University
Wei Liu
Taijun Pan
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School of Materials Science and Engineering, Changzhou UniversitySchool of Materials Science and Engineering, Changzhou University
Taijun Pan
Xingbo Han
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Shanghai Institute of Applied Physics, Chinese Academy of SciencesSchool of Materials Science and Engineering, Changzhou University
Xingbo Han
Lijun Lv
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Shanghai Institute of Applied Physics, Chinese Academy of SciencesSchool of Materials Science and Engineering, Changzhou University