Investigation of the hydrogen interaction with Ti0.9Zr0.1Mn1.3V0.7 by means of the calorimetric method

被引：7
|
作者：
Anikina, E. Yu. [1 ]
Verbetsky, V. N. [1 ]
机构：
[1] Lomonosou Moscow State Univ, Chem Dept Moscow, Moscow 119991, Russia
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2016年 / 41卷 / 27期
关键词：
Intermetallic compound; Hydride; Ti0.9Zr0.1Mn1.3V0.7-H-2; system; Calorimetry;
D O I：
10.1016/j.ijhydene.2015.12.126
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the present work we studied the hydrogen interaction with the stoichiometric Ti0.9Zr0.1Mn1.3V0.7 Laves phase compound C14 at pressure up to 50 atm and the temperature range from 52 to 130 degrees C by means of calorimetric method and plotting of pressure composition isotherms. The processes of hydrogen absorption and desorption were carried out. The findings enabled us to draw the following conclusions: 1) the experimental temperature influences the thermodynamic parameters of studied processes and 2) depending on reaction conditions the formation of one or two hydride phases takes place. (C) 2015 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：11520 / 11525
页数：6
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