Poly[[[μ2-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ2N3:N3′](μ2-2,6-dimethylpyridine-3,5-dicarboxylato-κ2O3:O5)zinc] dihydrate]

被引：0

作者：

Yue, Yu-Mei ^{[1
]}

Qian, Lei ^{[2
]}

Zhu, Zheng-Hao ^{[3
]}

Wang, Cheng ^{[4
]}

Gao, Ting ^{[4
]}

机构：

[1] Heilongjiang Univ, Pesticide Engn Res Ctr Heilongjiang Prov, Harbin 150080, Peoples R China

[2] Daqing Oil Field Water Supply Co, Inst Source Water Res, Daqing 163458, Peoples R China

[3] Dionex China Ltd, Dept Serv, Beijing 100029, Peoples R China

[4] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

COORDINATION POLYMERS; LIGANDS;

D O I：

10.1107/S1600536811039481

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title coordination polymer, {[Zn(C9H7NO4)(C10H14N4)]center dot 2H(2)O}(n), the Zn-II ion displays a distorted tetrahedral geometry with two imidazole N atoms from two 1,1'-(butane-1,4-diyl)bis(imidazole) (bbi) ligands and two carboxylate O atoms from two 2,6-dimethylpyridine-3,5-dicarboxylate (dpdc) ligands. The bbi and dpdc ligands bridge the Zn-II ions, forming layers parallel to (011). O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds and pi-pi interactions between the imidazole rings [centroid-centroid distance = 3.807 (5) angstrom] connect the layers. Two of the three uncoordinated water molecules are disordered, each over two 0.25-occupancy positions.

引用

页码：M1471 / U1538

页数：11

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