Poly[[[μ2-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ2N3:N3′](μ2-2,6-dimethylpyridine-3,5-dicarboxylato-κ2O3:O5)zinc] dihydrate]

被引：0
|
作者：
Yue, Yu-Mei [1 ]
Qian, Lei [2 ]
Zhu, Zheng-Hao [3 ]
Wang, Cheng [4 ]
Gao, Ting [4 ]
机构：
[1] Heilongjiang Univ, Pesticide Engn Res Ctr Heilongjiang Prov, Harbin 150080, Peoples R China
[2] Daqing Oil Field Water Supply Co, Inst Source Water Res, Daqing 163458, Peoples R China
[3] Dionex China Ltd, Dept Serv, Beijing 100029, Peoples R China
[4] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
COORDINATION POLYMERS; LIGANDS;
D O I：
10.1107/S1600536811039481
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title coordination polymer, {[Zn(C9H7NO4)(C10H14N4)]center dot 2H(2)O}(n), the Zn-II ion displays a distorted tetrahedral geometry with two imidazole N atoms from two 1,1'-(butane-1,4-diyl)bis(imidazole) (bbi) ligands and two carboxylate O atoms from two 2,6-dimethylpyridine-3,5-dicarboxylate (dpdc) ligands. The bbi and dpdc ligands bridge the Zn-II ions, forming layers parallel to (011). O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds and pi-pi interactions between the imidazole rings [centroid-centroid distance = 3.807 (5) angstrom] connect the layers. Two of the three uncoordinated water molecules are disordered, each over two 0.25-occupancy positions.
引用
收藏
页码：M1471 / U1538
页数：11
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