Inter- and intra-molecular hydrogen bonding in bis(2-amino-5-fluoro-3-methylphenyl)disulfide

被引：0

作者：

Drake, J. E. ^{[3
]}

Hursthouse, M. B. ^{[2
]}

Light, M. E. ^{[2
]}

Maheshwari, R. ^{[1
]}

Ojha, K. G. ^{[1
]}

Ratnani, R. ^{[1
]}

机构：

[1] MDS Univ, Dept Pure & Appl Chem, Ajmer 305009, India

[2] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

[3] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2008年 / 38卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

synthesis; structure; hydrogen bonding; disulfide;

D O I：

10.1007/s10870-008-9353-7

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Bis(2-amino-5-fluoro-3-methylphenyl)disulfide was obtained by oxidation of 2-amino-5-fluoro-3-methylbenzenethiol and was characterized by elemental analysis, IR and H-1-NMR spectroscopy. The X-ray structure was determined. Crystal data: C14H14N2F2S2: Monoclinic, P2(1)/n, a = 11.8268(3), b = 9.5770(3), c = 12.3977(3) angstrom, beta = 98.079(2)degrees, V = 1390.29(7) angstrom, Z = 4. The supramolecular structure arises because the NH2 groups form three center S center dot center dot center dot H center dot center dot center dot F hydrogen bonds and two center N-H center dot center dot center dot F and N-H center dot center dot center dot S hydrogen bonds.

引用

页码：553 / 556

页数：4

共 50 条

[41] Cis-[PtCl2(p-TPPTP(H)7)2]Cl2•4H2O•(CH3CH(OH)CH3):: a platinum phosphine complex exhibiting both inter- and intra-molecular hydrogen bonding
Schull, TL
Butcher, R
Dressick, WJ
Brandow, SL
Byington, LK
Knight, DA
POLYHEDRON, 2004, 23 (08) : 1375 - 1378
[42] TAUTOMERIC PYRIDINES .22. EFFECT OF INTRA-MOLECULAR HYDROGEN-BONDING ON THE TAUTOMERIC STRUCTURE OF 4-AMINO-1,10-PHENANTHROLINES
COOK, MJ
KATRITZKY, AR
NADJI, S
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1978, (12): : 1215 - 1222
[43] Evidence for the Preservation of Native Inter- and Intra-Molecular Hydrogen Bonds in the Desolvated FK-Binding Protein•FK506 Complex Produced by Electrospray Ionization
Hopper, Jonathan T. S.
Rawlings, Andrew
Afonso, Jose P.
Channing, Deborah
Layfield, Robert
Oldham, Neil J.
JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2012, 23 (10) : 1757 - 1767
[44] IR STUDIES OF SOLVENT EFFECT ON, AND STABILITY OF, INTRA-MOLECULAR HYDROGEN-BONDING IN 2-(N-METHYLCARBOXYAMIDO)-QUINOLINE
DZIEMBOWSKA, T
SZAFRAN, M
BULLETIN DE L ACADEMIE POLONAISE DES SCIENCES-SERIE DES SCIENCES CHIMIQUES, 1979, 27 (04): : 273 - 280
[45] Effects of inter- and intramolecular hydrogen bonding upon the structure and photoisomerization of 3-(2-pyridyl)propenamides
1600, (114):
[46] Comprehensive study on the topological properties of 5-Amino-2-Methyl Benzene Sulfonamide involving inter and intra molecular hydrogen bonds
Anzline, C.
Sivakumar, P.
Israel, S.
Sujatha, K.
JOURNAL OF MOLECULAR STRUCTURE, 2020, 1201
[47] PECULIARITIES OF THE 2-ARYL-3-AROYLAZIRIDINE STRUCTURE AND PROPERTIES STIPULATED BY INTRA-MOLECULAR HYDROGEN-BOND
ORLOV, VD
YAREMENKO, FG
SUROV, YN
LAVRUSHIN, VF
DOPOVIDI AKADEMII NAUK UKRAINSKOI RSR SERIYA B-GEOLOGICHNI KHIMICHNI TA BIOLOGICHNI NAUKI, 1979, (11): : 931 - 934
[48] Electrically conducting amorphous molecular materials:: preparation and electrical conductivities of chemically doped 2,5-bis{4-[bis(4-methylphenyl)amino]phenyl}thiophene and 5,5′-bis{4-[bis(4-methylphenyl)amino]phenyl}-2,2′-bithiophene
Ishihara, M
Noda, T
Kageyama, H
Nakano, H
Shirota, Y
SYNTHETIC METALS, 2001, 120 (1-3) : 795 - 796
[49] UNUSUAL CONFORMATION OF A DIHYDROPYRAN SHOWING ABNORMALLY WEAK INTRA-MOLECULAR HYDROGEN-BONDING CIS AND TRANS 2-PHENYL-3-HYDROXY DIPHENYL METHYL CHROMAN
BAERT, F
FOURET, R
SLIWA, M
SLIWA, H
ACTA CRYSTALLOGRAPHICA SECTION A, 1978, 34 : S290 - S290
[50] Effect of Intramolecular Hydrogen Bonding on Photocleavage Reaction of (3-Benzazolyl-2-hydroxy-5-methylphenyl) Methyl Acetate
Honda, Takuya
Ishida, Yuka
Arai, Tatsuo
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2016, 89 (11) : 1321 - 1327

← 1 2 3 4 5 →