Inter- and intra-molecular hydrogen bonding in bis(2-amino-5-fluoro-3-methylphenyl)disulfide

被引：0
|
作者：
Drake, J. E. [3 ]
Hursthouse, M. B. [2 ]
Light, M. E. [2 ]
Maheshwari, R. [1 ]
Ojha, K. G. [1 ]
Ratnani, R. [1 ]
机构：
[1] MDS Univ, Dept Pure & Appl Chem, Ajmer 305009, India
[2] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
[3] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2008年 / 38卷 / 07期
基金：
英国工程与自然科学研究理事会;
关键词：
synthesis; structure; hydrogen bonding; disulfide;
D O I：
10.1007/s10870-008-9353-7
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Bis(2-amino-5-fluoro-3-methylphenyl)disulfide was obtained by oxidation of 2-amino-5-fluoro-3-methylbenzenethiol and was characterized by elemental analysis, IR and H-1-NMR spectroscopy. The X-ray structure was determined. Crystal data: C14H14N2F2S2: Monoclinic, P2(1)/n, a = 11.8268(3), b = 9.5770(3), c = 12.3977(3) angstrom, beta = 98.079(2)degrees, V = 1390.29(7) angstrom, Z = 4. The supramolecular structure arises because the NH2 groups form three center S center dot center dot center dot H center dot center dot center dot F hydrogen bonds and two center N-H center dot center dot center dot F and N-H center dot center dot center dot S hydrogen bonds.
引用
收藏
页码：553 / 556
页数：4
相关论文
共 50 条
  • [31] Extension of the B3LYP-dispersion-correcting potential approach to the accurate treatment of both inter- and intra-molecular interactions
    DiLabio, Gino A.
    Koleini, Mohammad
    Torres, Edmanuel
    THEORETICAL CHEMISTRY ACCOUNTS, 2013, 132 (10) : 1 - 13
  • [32] Quinazolines with intra-molecular hydrogen bonding scaffold (iMHBS) as PI3K/mTOR dual inhibitors
    Liu, Kevin K. C.
    Huang, Xiaojun
    Bagrodia, Shubha
    Chen, Jeffrey H.
    Greasley, Samantha
    Cheng, Hengmiao
    Sun, Shaoxian
    Knighton, Dan
    Rodgers, Caroline
    Rafidi, Kristina
    Zou, Aihua
    Xiao, Jiezhan
    Yan, Shengyong
    BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2011, 21 (04) : 1270 - 1274
  • [33] The effect of Ru/C and MgCl2 on the cleavage of inter- and intra-molecular linkages during cornstalk hydrolysis residue valorization
    Wei Lv
    Yuhe Liao
    Yuting Zhu
    Jing Liu
    Changhui Zhu
    Chenguang Wang
    Ying Xu
    Qi Zhang
    Guanyi Chen
    Longlong Ma
    Cellulose, 2020, 27 : 799 - 823
  • [34] The first examples of supramolecular discotic C3h tris(N-salicylideneamine)s featuring inter- and intra-molecular H-bonding: synthesis and characterization
    Yelamaggad, C. V.
    Prabhu, Rashmi
    Rao, D. S. Shankar
    Prasad, S. Krishna
    TETRAHEDRON LETTERS, 2010, 51 (34) : 4579 - 4583
  • [35] The effect of Ru/C and MgCl2 on the cleavage of inter- and intra-molecular linkages during cornstalk hydrolysis residue valorization
    Lv, Wei
    Liao, Yuhe
    Zhu, Yuting
    Liu, Jing
    Zhu, Changhui
    Wang, Chenguang
    Xu, Ying
    Zhang, Qi
    Chen, Guanyi
    Ma, Longlong
    CELLULOSE, 2020, 27 (02) : 799 - 823
  • [36] 5,5''-bis{4-[bis(4-methylphenyl)amino]phenyl}-2,2':5',2''-terthiophene and 5,5'''-bis{4-[bis(4-methylphenyl)amino]phenyl}-2,2':5',2'':5'',2'''-quaterthiophene as a novel family of amorphous molecular materials
    Noda, T
    Imae, I
    Noma, N
    Shirota, Y
    ADVANCED MATERIALS, 1997, 9 (03) : 239 - +
  • [37] Isomerization and inter/intra-molecular CO exchange in Ru(biPSi)(H)(CO)2 [biPSi = bis(diphenylphosphinopropyl)silyl].
    Zhou, XB
    Stobart, SR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U31 - U31
  • [38] Extension of the B3LYP–dispersion-correcting potential approach to the accurate treatment of both inter- and intra-molecular interactions
    Gino A. DiLabio
    Mohammad Koleini
    Edmanuel Torres
    Theoretical Chemistry Accounts, 2013, 132
  • [39] Inter- and intra-molecular energy transfer during sensitization of Eu(DBM)3Phen luminescence by Tb(DBM)3Phen in PMMA
    Luo, Yanhua
    Yan, Qing
    Wu, Si
    Wu, Wenxuan
    Zhang, Qijin
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2007, 191 (2-3) : 91 - 96
  • [40] Inter-/intra-molecular synergism improve self-assembly behavior of hydroxamate-modified amino acid surfactant for flocculation of micro-fine particles
    Fei, Lingyun
    Sun, Qing
    Wang, Shuai
    Cao, Zhanfang
    Sun, Hongyu
    Zhong, Hong
    Ma, Xin
    CHEMICAL ENGINEERING SCIENCE, 2023, 282
12345