Inter- and intra-molecular hydrogen bonding in bis(2-amino-5-fluoro-3-methylphenyl)disulfide

被引：0
|
作者：
Drake, J. E. [3 ]
Hursthouse, M. B. [2 ]
Light, M. E. [2 ]
Maheshwari, R. [1 ]
Ojha, K. G. [1 ]
Ratnani, R. [1 ]
机构：
[1] MDS Univ, Dept Pure & Appl Chem, Ajmer 305009, India
[2] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
[3] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2008年 / 38卷 / 07期
基金：
英国工程与自然科学研究理事会;
关键词：
synthesis; structure; hydrogen bonding; disulfide;
D O I：
10.1007/s10870-008-9353-7
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Bis(2-amino-5-fluoro-3-methylphenyl)disulfide was obtained by oxidation of 2-amino-5-fluoro-3-methylbenzenethiol and was characterized by elemental analysis, IR and H-1-NMR spectroscopy. The X-ray structure was determined. Crystal data: C14H14N2F2S2: Monoclinic, P2(1)/n, a = 11.8268(3), b = 9.5770(3), c = 12.3977(3) angstrom, beta = 98.079(2)degrees, V = 1390.29(7) angstrom, Z = 4. The supramolecular structure arises because the NH2 groups form three center S center dot center dot center dot H center dot center dot center dot F hydrogen bonds and two center N-H center dot center dot center dot F and N-H center dot center dot center dot S hydrogen bonds.
引用
收藏
页码：553 / 556
页数：4
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