Regioselective substitution in α-bromo-β-butoxyvinyl trifluoromethyl ketone by N-nucleophiles

被引:9
|
作者
Rulev, AY
Fedorov, SV
Nenajdenko, VG
Balenkova, ES
Voronkov, MG
机构
[1] Russian Acad Sci, Siberian Div, A E Favorsky Inst Chem, Irkutsk 664003, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
关键词
alpha; beta-unsaturated trifluoromethyl ketones; N-nucleophiles; nucleophilic vinylic substitution;
D O I
10.1023/B:RUCB.0000011895.89292.dd
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of alpha-bromo-beta-butoxyvinyl trifluoromethyl ketone with N-nucleophiles proceeds regiospecifically to give amino enones of the push-pull type.
引用
收藏
页码:2287 / 2289
页数:3
相关论文
共 22 条
  • [1] Regioselective substitution in α-bromo-β-butoxyvinyl trifluoromethyl ketone by N-nucleophiles
    A. Yu. Rulev
    S. V. Fedorov
    V. G. Nenajdenko
    E. S. Balenkova
    M. G. Voronkov
    Russian Chemical Bulletin, 2003, 52 : 2287 - 2289
  • [2] Regioselective ring opening of [(perfluoroalkyl)methyl] oxiranes with N-nucleophiles
    Conte, L
    Maniero, F
    Zaggia, A
    Bertani, R
    Garnbaretto, G
    Berton, A
    Seraglia, R
    JOURNAL OF FLUORINE CHEMISTRY, 2005, 126 (9-10) : 1274 - 1280
  • [3] Synthesis of new α-trifluoromethyl substituted formamidines framework by using N-nucleophiles and N,S bidentate nucleophiles
    Darehkordi, Ali
    Rahmani, Fariba
    JOURNAL OF FLUORINE CHEMISTRY, 2016, 190 : 41 - 47
  • [4] Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation
    Yang, Qin
    Wang, Qingfu
    Yu, Zhengkun
    CHEMICAL SOCIETY REVIEWS, 2015, 44 (08) : 2305 - 2329
  • [5] REACTION OF 5-BROMO-5'-DEOXY-5'-FLUORO-URIDINE WITH O-NUCLEOPHILES, N-NUCLEOPHILES AND S-NUCLEOPHILES
    HERRMANN, G
    CECH, D
    KOWOLLIK, G
    LANGEN, P
    ZEITSCHRIFT FUR CHEMIE, 1979, 19 (10): : 376 - 377
  • [6] Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with O- and N-nucleophiles
    E. V. Stukan’
    S. V. Makarenko
    G. A. Berkova
    V. M. Berestovitskaya
    Russian Journal of General Chemistry, 2010, 80 : 2460 - 2465
  • [7] Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with O- and N-nucleophiles
    Stukan, E. V.
    Makarenko, S. V.
    Berkova, G. A.
    Berestovitskaya, V. M.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2010, 80 (12) : 2460 - 2465
  • [8] The first NHC-induced regioselective introduction of C- and N-nucleophiles in to Baylis-Hillman enals
    Rai, Vijai K.
    Sahu, Ganeshwar P.
    Rai, Ankita
    TETRAHEDRON LETTERS, 2015, 56 (21) : 2664 - 2668
  • [9] Mild and Efficient Iodine-Catalyzed Direct Substitution of Hydroxy Group of Alcohols with C- and N-Nucleophiles
    Liu, Zhe
    Wang, Dong
    Chen, Yongjun
    LETTERS IN ORGANIC CHEMISTRY, 2011, 8 (01) : 73 - 80
  • [10] Regioselective Aromatic Nucleophilic Substitution in N-Aryl-2-nitrosoanilines with Oxygen and Nitrogen Nucleophiles
    Wrobel, Zbigniew
    Stachowka, Karolina
    Kwast, Andrzej
    SYNTHESIS-STUTTGART, 2013, 45 (01): : 127 - 133