Regioselective substitution in α-bromo-β-butoxyvinyl trifluoromethyl ketone by N-nucleophiles

被引：9
|
作者：
Rulev, AY
Fedorov, SV
Nenajdenko, VG
Balenkova, ES
Voronkov, MG
机构：
[1] Russian Acad Sci, Siberian Div, A E Favorsky Inst Chem, Irkutsk 664003, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2003年 / 52卷 / 10期
关键词：
alpha; beta-unsaturated trifluoromethyl ketones; N-nucleophiles; nucleophilic vinylic substitution;
D O I：
10.1023/B:RUCB.0000011895.89292.dd
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of alpha-bromo-beta-butoxyvinyl trifluoromethyl ketone with N-nucleophiles proceeds regiospecifically to give amino enones of the push-pull type.
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页码：2287 / 2289
页数：3
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