Enantioselective hydrogenation of alkenes and imines by a gold catalyst

被引：118
|
作者：
González-Arellano, C
Corma, A
Iglesias, M
Sánchez, F
机构：
[1] CSIC, Inst Quim Organ Gen, E-28006 Madrid, Spain
[2] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[3] CSIC, Inst Ciencia Mat Madrid, Madrid 28049, Spain
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 27期
关键词：
D O I：
10.1039/b505271h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new neutral dimeric gold( I) complex bearing the 1,2-bis[( 2R,5R)-2,5-dimethylphospholanebenzene] [(R,R)-Me-Duphos] ligand has been synthesized which catalyzes the asymmetric hydrogenation of alkenes and imines under mild reaction conditions.
引用
收藏
页码：3451 / 3453
页数：3
相关论文
共 50 条
  • [31] On the Mechanism of Iridium-Catalyzed Asymmetric Hydrogenation of Imines and Alkenes: A Theoretical Study
    Hopmann, Kathrin Helen
    Bayer, Annette
    ORGANOMETALLICS, 2011, 30 (09) : 2483 - 2497
  • [32] Regioselective and Enantioselective Nickel-Catalyzed Intermolecular Reductive Coupling of Aliphatic Alkenes with Imines
    Chen, Zhi-Hong
    Gu, Li-Jie
    Wang, Biao
    Xiao, Li-Jun
    Ye, Mengchun
    Zhou, Qi-Lin
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (22) : 14915 - 14921
  • [33] Iridium-catalyzed enantioselective hydrogenation of imines with xylose diphosphite and diphosphinite ligands
    Guiu, E
    Muñoz, B
    Castillón, S
    Claver, C
    ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) : 169 - 171
  • [34] Direct Enantioselective Addition of Alkynes to Imines by a Highly Efficient Palladacycle Catalyst
    Pfeffer, Camilla
    Probst, Patrick
    Wannenmacher, Nick
    Frey, Wolfgang
    Peters, Rene
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (35)
  • [35] HYDROGENATION OF ALKENES OVER A COBALT-MOLYBDENUM-ALUMINA CATALYST
    UCHYTIL, J
    JAKUBICKOVA, E
    KRAUS, M
    JOURNAL OF CATALYSIS, 1980, 64 (01) : 143 - 149
  • [36] NOVEL POLYMER-RHODIUM COMPLEX AS HYDROGENATION CATALYST OF ALKENES
    NAKAMURA, Y
    HIRAI, H
    CHEMISTRY LETTERS, 1975, (08) : 823 - 828
  • [37] Monte-Carlo model for the hydrogenation of alkenes on metal catalyst
    Duca, D
    Baranyai, P
    Vidóczy, T
    JOURNAL OF COMPUTATIONAL CHEMISTRY, 1998, 19 (04) : 396 - 403
  • [38] An efficient hydrogenation of various alkenes using scrap automobile catalyst
    Zengin, Mustafa
    Genc, Hayriye
    Demirci, Tuna
    Arslan, Mustafa
    Kucukislamoglu, Mustafa
    TETRAHEDRON LETTERS, 2011, 52 (18) : 2333 - 2335
  • [39] Jacobsen catalyst anchored onto an activated carbon as an enantioselective heterogeneous catalyst for the epoxidation of alkenes
    Silva, AR
    Freire, C
    de Castro, B
    CARBON, 2004, 42 (14) : 3027 - 3030
  • [40] Asymmetric hydrogenation of cyclic imines with an ionic Cp*Rh(III) catalyst
    Li, Chaoqun
    Xiao, Jianliang
    Journal of the American Chemical Society, 2008, 130 (40): : 13208 - 13209
12345