Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO2 reduction under visible light

被引：178
|
作者：
Sun, Dengrong [1 ]
Gao, Yanhong [1 ]
Fu, Jinlong [1 ]
Zeng, Xianchong [2 ]
Chen, Zhongning [2 ]
Li, Zhaohui [1 ]
机构：
[1] Fuzhou Univ, Res Inst Photocatalysis, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 13期
关键词：
METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE; ARYL HALIDES; OXIDATION; LIGAND; PHOTOREDUCTION; CATALYSTS; INSERTION;
D O I：
10.1039/c4cc09797a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A MOF-253 supported active Ru carbonyl complex (MOF-253-Ru(CO)(2)Cl-2) was constructed for photocatalytic CO2 reduction under visible light irradiation. Its performance can be further improved by immobilization as a photosensitizer. This study highlights the great potential of using MOFs as a solid ligand and platform for the assembly of a complicated catalytic system.
引用
收藏
页码：2645 / 2648
页数：4
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