Novel phthalocyanines with naphthalenic substituents

被引：16
|
作者：
Sener, M. Kasim [2 ]
Guel, Ahmet [1 ]
Kocak, Makbule Burkut [1 ]
机构：
[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
[2] Yildiz Tech Univ, Dept Chem, TR-34210 Istanbul, Turkey
来源：
TRANSITION METAL CHEMISTRY | 2008年 / 33卷 / 07期
关键词：
D O I：
10.1007/s11243-008-9125-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Phthalocyanines with four naphthyl-malonic ester groups on the periphery were synthesized by cyclotetramerization of 4-(1,1-dicarbethoxy-2-(1-naphthyl)-ethyl)-phthalonitrile. The new compounds were characterized by spectroscopic methods. The electronic spectra exhibit intense pi-pi* transitions from the naphthyl moiety together with the characteristic Q and B bands of the phthalocyanine core. The electrochemical properties of the 2,9,17,23-tetra-(1,1-(dicarbethoxy)-2-(1-naphthyl)-ethyl) phthalocyaninato copper(II) complex were studied by cyclic voltammetry.
引用
收藏
页码：867 / 872
页数：6
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