Novel phthalocyanines with naphthalenic substituents

被引:16
|
作者
Sener, M. Kasim [2 ]
Guel, Ahmet [1 ]
Kocak, Makbule Burkut [1 ]
机构
[1] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey
[2] Yildiz Tech Univ, Dept Chem, TR-34210 Istanbul, Turkey
关键词
D O I
10.1007/s11243-008-9125-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Phthalocyanines with four naphthyl-malonic ester groups on the periphery were synthesized by cyclotetramerization of 4-(1,1-dicarbethoxy-2-(1-naphthyl)-ethyl)-phthalonitrile. The new compounds were characterized by spectroscopic methods. The electronic spectra exhibit intense pi-pi* transitions from the naphthyl moiety together with the characteristic Q and B bands of the phthalocyanine core. The electrochemical properties of the 2,9,17,23-tetra-(1,1-(dicarbethoxy)-2-(1-naphthyl)-ethyl) phthalocyaninato copper(II) complex were studied by cyclic voltammetry.
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页码:867 / 872
页数:6
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