The first fullerene-metal sandwich complex:: An unusually strong electronic communication between two C60 cages

被引：66
|
作者：
Lee, K
Song, H
Kim, B
Park, JT [1 ]
Park, S
Choi, MG
机构：
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Sch Mol Sci BK21, Taejon 305701, South Korea
[3] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
[4] Yonsei Univ, Mol Struct Lab, Seoul 120749, South Korea
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 12期
关键词：
D O I：
10.1021/ja017496k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of Rh6(CO)9(dppm)2(μ3-η2,η2,η2-C60) (1) with C60 in refluxing chlorobenzene followed by treatment with CNR (R = CH2C6H5) at room temperature affords the first fullerene-metal sandwich complex Rh6(CO)5(dppm)2(CNR)(μ3-η2,η2,η2-C60)2 (2). Compound 2 has been characterized by an X-ray diffraction study. Electrochemical study of 2 reveals six well-separated reversible redox couples localized at C60 cages due to a strong electronic communication between the two C60 centers via the Rh6 cluster spacer. Copyright © 2002 American Chemical Society.
引用
收藏
页码：2872 / 2873
页数：2
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