First ionic multi-component complex of fullerene C60(CN)2 with Co(II)tetraphenylporphyrin and bis(benzene)chromium

被引：6
|
作者：
Konarev, DV [1 ]
Khasanov, SS
Otsuka, A
Yoshida, Y
Saito, G
机构：
[1] Kyoto Univ, Grad Sch Engn, Div Chem, Sakyo Ku, Kyoto 6068502, Japan
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia
[3] Russian Acad Sci, Inst Solid State Phys, Chernogolovka 142432, Moscow Region, Russia
来源：
SYNTHETIC METALS | 2003年 / 133卷
关键词：
multi-component complexes; fullerides; porphyrins; bis(benzene)chromium;
D O I：
10.1016/S0379-6779(02)00426-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
First ionic multi-component complex CoTPP.2C(60)(CN)(2).2Bz(2)Cr.3C(6)H(4)Cl(2) (COTPP: cobalt(II)tetraphenylporphyrin; Bz(2)Cr: bis(benzene)chromium; C6H4Cl2: o-dichlorobenzene) has been synthesized. CoTPP molecules and fullerides form channels providing the accommodation of Bz(2)Cr(.+) and C6H4Cl2. For the first time it is shown that, in contrast to the neutral fullerenes, the cobalt atom of CoTPP coordinates to the fullerene anions with short Co...C(fullerene) distance of 2.28 Angstrom. CoTPP-C-60(CN)(2)(-) anion is diamagnetic according to the EPR- and SQUID-measurements. The shape of the starting molecule retains at the formation of the C-60(CN)(2)(.-) anion-radicals. The length of Cequivalent toN bonds are 1.143 and 1.161 Angstrom. (C) 2002 Elsevier Science B.V. All rights reserved.
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收藏
页码：707 / 709
页数：3
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