First ionic multi-component complex of fullerene C60(CN)2 with Co(II)tetraphenylporphyrin and bis(benzene)chromium

被引：6

作者：

Konarev, DV ^{[1
]}

Khasanov, SS

Otsuka, A

Yoshida, Y

Saito, G

机构：

[1] Kyoto Univ, Grad Sch Engn, Div Chem, Sakyo Ku, Kyoto 6068502, Japan

[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

[3] Russian Acad Sci, Inst Solid State Phys, Chernogolovka 142432, Moscow Region, Russia

来源：

SYNTHETIC METALS | 2003年 / 133卷

关键词：

multi-component complexes; fullerides; porphyrins; bis(benzene)chromium;

D O I：

10.1016/S0379-6779(02)00426-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

First ionic multi-component complex CoTPP.2C(60)(CN)(2).2Bz(2)Cr.3C(6)H(4)Cl(2) (COTPP: cobalt(II)tetraphenylporphyrin; Bz(2)Cr: bis(benzene)chromium; C6H4Cl2: o-dichlorobenzene) has been synthesized. CoTPP molecules and fullerides form channels providing the accommodation of Bz(2)Cr(.+) and C6H4Cl2. For the first time it is shown that, in contrast to the neutral fullerenes, the cobalt atom of CoTPP coordinates to the fullerene anions with short Co...C(fullerene) distance of 2.28 Angstrom. CoTPP-C-60(CN)(2)(-) anion is diamagnetic according to the EPR- and SQUID-measurements. The shape of the starting molecule retains at the formation of the C-60(CN)(2)(.-) anion-radicals. The length of Cequivalent toN bonds are 1.143 and 1.161 Angstrom. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：707 / 709

页数：3

共 28 条

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Konarev, Dmitri V.
Khasanov, Salavat S.
Mukhamadieva, Guzeliya R.
Zorina, Leokadia V.
Otsuka, Akihiro
Yamochi, Hideki
Saito, Gunzi
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[22] Design of Molecular and Ionic Complexes of Fullerene C60 with Metal(II) Octaethylporphyrins, MIIOEP (M = Zn, Co, Fe, and Mn) Containing Coordination M-N(ligand) and M-C(C60-) Bonds
Konarev, Dmitri V.
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[23] Crystal structure and magnetic properties of an ionic C60 complex with decamethylcobaltocene:: (Cp*2Co)2C60(C6H4Cl2, C6H5CN)2.: Singlet-triplet transitions in the C602- anion
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[24] Mononuclear Coordination Complexes of Fullerene C60 with Zerovalent Cobalt Having S=1/2 Spin State: Co(η2-C60)(L)(C6H5CN)•(o-C6H4Cl2) (L=1,2-bis(diphenylphosphino)ethane and 1,1′-bis(diphenylphosphino)ferrocene)
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[25] Simulations of Multi-Photon Absorption Spectra for Fullerene Derivatives C60 > C2H4NH3(Polyaniline)n Based on First-principle Calculations
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[26] Synthesis and crystal structure of a molybdenum complex of fullerene, [Mo(η2–C60)(CO)2(dpphen)(dbf)·0.63CS2] (dpphen = 4,7-diphenyl-1,10-phenanthroline; dbf = dibutyl fumarate)
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[28] First synthesis of a new fullerene oximes bis(9-[hydroxo]-1-[1′-hydroxymino-2′-oxo-2′-alkyl-ethyl])1,9-dihydro-[C60-Ih][5,6]fullerenes via reaction of C60 with ketones and NaNO2 promoted by HCl
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