Synthesis and Reaction of Fullerene C70 Encapsulating Two Molecules of H2

被引：114
|
作者：
Murata, Michihisa [1 ]
Maeda, Shuhei [1 ]
Morinaka, Yuta [1 ]
Murata, Yasujiro [1 ,2 ]
Komatsu, Koichi [1 ]
机构：
[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan
[2] Japan Sci & Technol Agcy, PRESTO, Kyoto 6110011, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 47期
关键词：
D O I：
10.1021/ja8076846
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New endohedral fullerene C-70 encapsulating one and two H-2 molecules) has been synthesized by organic reactions, the so-called "molecular surgery" method, and the first organic derivatization of H-2@C-70 and (H-2)(2)@C-70 has been conducted. Although the interaction between inner H-2 and outer C-70 is rather weak, (H-2)(2)@C-70 exhibits smaller equilibrium constants in the Diels-Alder reaction with 9,10-dimethylanthracene than those of H-2@C-70.
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收藏
页码：15800 / +
页数：3
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