Synthesis and Reaction of Fullerene C70 Encapsulating Two Molecules of H2

被引：114

作者：

Murata, Michihisa ^{[1
]}

Maeda, Shuhei ^{[1
]}

Morinaka, Yuta ^{[1
]}

Murata, Yasujiro ^{[1
,2
]}

Komatsu, Koichi ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Kyoto 6110011, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 47期

关键词：

D O I：

10.1021/ja8076846

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New endohedral fullerene C-70 encapsulating one and two H-2 molecules) has been synthesized by organic reactions, the so-called "molecular surgery" method, and the first organic derivatization of H-2@C-70 and (H-2)(2)@C-70 has been conducted. Although the interaction between inner H-2 and outer C-70 is rather weak, (H-2)(2)@C-70 exhibits smaller equilibrium constants in the Diels-Alder reaction with 9,10-dimethylanthracene than those of H-2@C-70.

引用

页码：15800 / +

页数：3

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