Pentacarbonyl[N,N-dimethyl-N′-( 5-{2-[5-(4-pyridyl-ethynyl) thiophen-2-yl]vinyl}thiophen-2-ylmethyl-ene) benzene-1,4-diamine]tungsten(0)

被引:0
|
作者
Huang, PH [1 ]
Huang, TH
Shen, JY
Wen, YS
机构
[1] Kang Ning Jr Coll Med Care & Management, Taipei, Taiwan
[2] Acad Sinica, Inst Chem, Taipei, Taiwan
[3] Natl Taiwan Normal Univ, Dept Chem, Taipei, Taiwan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词
D O I
10.1107/S1600536806003576
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [W(C26H21N3S2)(CO)(5)], the geometry at the Watom is approximately octahedral, with the cis bond angles in the range 86.45 (13)-94.99 (12)degrees. The bond to the trans carbonyl is quite short [W-C = 1.953 (4) angstrom] and the equatorial W-CO bonds lie in the range 2.010 (4)-2.059 (4) angstrom.
引用
收藏
页码:M432 / M433
页数:2
相关论文
共 50 条
  • [31] Crystal structure of 2-(thiophen-2-yl)-1-(5-thioxo-4,5-dihydro-1,3,4-oxadiazol-2-yl)ethenyl]benzamide : N,N-dimethylformamide (1:1)
    Sharma, P.
    Subbulakshmi, K. N.
    Narayana, B.
    Sarojini, B. K.
    Kant, R.
    CRYSTALLOGRAPHY REPORTS, 2016, 61 (02) : 230 - 233
  • [32] Mass Spectra of New Heterocycles: XXVI. Electron Impact Ionization Study of N-(5-Amino­thiophen-2-yl)- and N-[2-(Methylsulfanyl)-1,3-thiazol-5-yl]­isothioureas
    L. V. Klyba
    E. R. Sanzheeva
    N. A. Nedolya
    O. A. Tarasova
    Russian Journal of Organic Chemistry, 2023, 59 : 1136 - 1143
  • [33] Crystal structure of (E)-5-((4-chlorophenyl) diazenyl)-2-(5-(4-fluorophenyl)-3-(thiophen-2-yl)-4,5-dihydro-1H-pyrazol-1-yl)-4-methylthiazole, C23H17ClFN5S2
    El-Hiti, Gamal A.
    Abdel-Wahab, Bakr F.
    Baashen, Mohammed
    Hegazy, Amany S.
    Kariuki, Benson M.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2017, 232 (01): : 157 - 158
  • [34] 2-(Biphenyl-4-yl)-5-[3-(4,5,6,7-tetrahydrothieno[3,2-c]pyridine-5-ylsulfonyl)thiophen-2-yl]-1,3,4-oxadiazole
    Fun, Hoong-Kun
    Hemamalini, Madhukar
    Rai, Sankappa
    Isloor, A. M.
    Shetty, Prakash
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2781 - +
  • [35] Crystal structure of (E)-1-(thiophen-2-yl)-N-(5-((triphenylstannyl)thio)-1,3,4-thiadiazol-2-yl)methanimine, C25H19N3S3Sn
    Sun, Junshan
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2019, 234 (03): : 493 - 494
  • [36] Optoelectronic of Properties of N1-[4-(Diethylamino)phenyl]-N4,N4-diethyl-N1-(thiophen-2-yl)benzene-1,4-diamine-Based (D-A2-π-A) Dyes with Enzothiadiazole/Dihydrothieno[3,4-b][1,4]dioxine as Auxiliary Acceptor for DSSCs Applications: DFT/TD-DFT Approach
    Olatunde, A. M.
    Adedokun, N. O.
    Owonikoko, A. D.
    Obiyenwa, G. K.
    Anthony, W. O.
    Semire, B.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2024, 94 (10) : 2710 - 2720
  • [37] The six-membered-ring azomethine N-((E)-{5-[(E)-(pyridin-3-ylimino)methyl]thiophen-2-yl}methylidene)pyridin-3-amine
    Bolduc, Andreanne
    Dufresne, Stephane
    Skene, W. G.
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2013, 69 : 1196 - +
  • [38] N-phenyl-N-{4-[5-(4-pyridyl)-1,3,4-oxadiazol-2-yl] phenyl} aniline
    Han, Li-Ping
    Li, Bin
    Liu, Jie
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O242 - U4756
  • [39] 2-(5-Bromopyridin-3-yl)-5-[3-(4,5,6,7-tetrahydrothieno[3,2-c]pyridine-5-ylsulfonyl)thiophen-2-yl]-1,3,4-oxadiazole
    Fun, Hoong-Kun
    Hemamalini, Madhukar
    Rai, Sankappa
    Isloor, A. M.
    Shetty, Prakash
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2743 - +
  • [40] N,N-Dimethyl-N′-[(1E,2E)-3-(4-nitrophenyl)prop-2-enylidene]benzene-1,4-diamine and N,N-dimethyl-4-[(1E,3E)-4-(4-nitrophenyl)buta-1,3-dienyl]-1-naphthylamine
    Nesterov, VV
    Suina, A
    Antipin, MY
    Timofeeva, TV
    Barlow, S
    Marder, SR
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 (11): : O625 - O628