Pentacarbonyl[N,N-dimethyl-N′-( 5-{2-[5-(4-pyridyl-ethynyl) thiophen-2-yl]vinyl}thiophen-2-ylmethyl-ene) benzene-1,4-diamine]tungsten(0)

被引：0
|
作者：
Huang, PH [1 ]
Huang, TH
Shen, JY
Wen, YS
机构：
[1] Kang Ning Jr Coll Med Care & Management, Taipei, Taiwan
[2] Acad Sinica, Inst Chem, Taipei, Taiwan
[3] Natl Taiwan Normal Univ, Dept Chem, Taipei, Taiwan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806003576
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [W(C26H21N3S2)(CO)(5)], the geometry at the Watom is approximately octahedral, with the cis bond angles in the range 86.45 (13)-94.99 (12)degrees. The bond to the trans carbonyl is quite short [W-C = 1.953 (4) angstrom] and the equatorial W-CO bonds lie in the range 2.010 (4)-2.059 (4) angstrom.
引用
收藏
页码：M432 / M433
页数：2
相关论文
共 50 条
  • [21] Deactivating effect of the pyridine n,π* states on the photoreactivity of 5-[2-(pyrid-n-yl)ethenyl]oxazole (n=2, 3 and 4)
    Botti, V.
    Elisei, F.
    Faraguna, F.
    Marinic, Z.
    Mazzucato, U.
    Sagud, I.
    Sindler-Kulyk, M.
    Spalletti, A.
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2016, 329 : 262 - 272
  • [22] 1-[5-(4,5-Dimethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl]ethanone and 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde
    Urdaneta, Neudo
    Nunez, Jesus
    Gonzalez, Teresa
    Briceno, Alexander
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2012, 68 : O213 - O215
  • [23] N '-[(5-Methyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)(thiophen-2-yl)methylidene]benzohydrazide
    Zhu, Hualing
    Zhu, Jinhua
    Bu, Luxia
    Shi, Jun
    Wang, Juan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1368 - +
  • [24] The synthesis, crystal structure and Hirshfeld surface analysis of the thiophene derivatives 5-(phenylsulfonyl)-5,6-dihydrobenzo[4,5]thieno[3,2-j]phenanthridine and (E)-N-{2-[2-(benzo[b]thiophen-2-yl)ethenyl]phenyl}-N-(prop-2-yn-1-yl)benzenesulfonamide
    Madhan, S.
    NizamMohideen, M.
    Pavunkumar, Vinayagam
    MohanaKrishnan, Arasambattu K.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2023, 79 : 521 - +
  • [25] Discovery of 1-(2,4-Dichlorophenyl)-4-ethyl-5-(5-(2-(4-(trifluoromethyl)phenyl)ethynyl)thiophen-2-yl)-N-(piperidin-1-yl)-1H-pyrazole-3-carboxamide as a Potential Peripheral Cannabinoid-1 Receptor Inverse Agonist
    Hung, Ming-Shiu
    Chang, Chun-Ping
    Li, Ting-Chieh
    Yeh, Teng-Kuang
    Song, Jen-Shin
    Lin, Yinchiu
    Wu, Chien-Huang
    Kuo, Po-Chu
    Amancha, Prashanth K.
    Wong, Ying-Chieh
    Hsiao, Wen-Chi
    Chao, Yu-Sheng
    Shia, Kak-Shan
    CHEMMEDCHEM, 2010, 5 (09) : 1439 - 1443
  • [26] Spectroscopic, crystallographic, and docking studies of 3,4-dimethyl-N-((thiophen-2-yl)methylene)isoxazol-5-amine Schiff base
    Kumar, Ch. Vijay
    Kumar, M. Pradeep
    Tejaswi, S.
    Shivaraj
    CRYSTALLOGRAPHY REPORTS, 2014, 59 (07) : 1029 - 1032
  • [27] Spectroscopic, crystallographic, and docking studies of 3,4-dimethyl-N-((thiophen-2-yl)methylene)isoxazol-5-amine Schiff base
    Ch. Vijay Kumar
    M. Pradeep Kumar
    S. Tejaswi
    Crystallography Reports, 2014, 59 : 1029 - 1032
  • [28] Crystal structure of 1-(4-fluorophenyl)-N-(5-((triphenylstannyl)thio)thiophen-2-yl)methanimine, C27H20FN3S2Sn
    Meng, Fankun
    Jia, Junying
    Liu, Hongsheng
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2018, 233 (01): : 129 - 130
  • [29] Crystal structure of 2-(thiophen-2-yl)-1-(5-thioxo-4,5-dihydro-1,3,4-oxadiazol-2-yl)ethenyl]benzamide : N,N-dimethylformamide (1 : 1)
    P. Sharma
    K. N. Subbulakshmi
    B. Narayana
    B. K. Sarojini
    R. Kant
    Crystallography Reports, 2016, 61 : 230 - 233
  • [30] Crystal structures of (Z)-5-[2-(benzo[b]thiophen-2-yl)-1-(3,5-dimethoxyphenyl)ethenyl]-1H-tetrazole and (Z)-5-[2-(benzo[b]thiophen-3-yl)-1-(3,4,5-trimethoxyphenyl)ethenyl]-1H-tetrazole
    Penthala, Narsimha Reddy
    Yadlapalli, Jaishankar K. B.
    Parkin, Sean
    Crooks, Peter A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 652 - +
12345