Crystal Growth of the Nanoporous Metal-Organic Framework HKUST-1 Revealed by In Situ Atomic Force Microscopy

被引：139

作者：

Shoaee, Maryiam ^{[1
]}

Anderson, Michael W. ^{[1
]}

Attfield, Martin P. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 44期

关键词：

atomic force microscopy; crystal growth; HKUST-1; metal-organic frameworks; microporous materials;

D O I：

10.1002/anie.200803460

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Watching crystals grow: In situ atomic force microscopy has been used to observe the crystal growth of the nanoporous metal-organic framework HKUST-1. This real-time study provides evidence that the growth of HKUST-1 under the given supersaturation conditions is through a surface nucleation mechanism and presents insight into the units of attachment during the growth of the 1.5 nm high steps on the crystal surface (see picture). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8525 / 8528

页数：4

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