Crystal Growth of the Nanoporous Metal-Organic Framework HKUST-1 Revealed by In Situ Atomic Force Microscopy

被引：139
|
作者：
Shoaee, Maryiam [1 ]
Anderson, Michael W. [1 ]
Attfield, Martin P. [1 ]
机构：
[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 44期
关键词：
atomic force microscopy; crystal growth; HKUST-1; metal-organic frameworks; microporous materials;
D O I：
10.1002/anie.200803460
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Watching crystals grow: In situ atomic force microscopy has been used to observe the crystal growth of the nanoporous metal-organic framework HKUST-1. This real-time study provides evidence that the growth of HKUST-1 under the given supersaturation conditions is through a surface nucleation mechanism and presents insight into the units of attachment during the growth of the 1.5 nm high steps on the crystal surface (see picture). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：8525 / 8528
页数：4
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