Chiron approach for the synthesis of (1S,2R,5R,7S)-2-hydroxy-exo-brevicomin

被引：17

作者：

Gautam, D ^{[1
]}

Kumar, DN ^{[1
]}

Rao, BV ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Div 3, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 05期

关键词：

D O I：

10.1016/j.tetasy.2006.02.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(1S,2R,5R,7S)-2-Hydroxy-exo-brevicomin ent-1 was synthesized from 1,2;5,6-di-O-isopropylidene-(D)-glucose in seven steps. The key reaction in our synthesis is the formation of bicyclic ketal 7 under acid mediated acetal exchange of a 1,2-acetonide Of D-glucose derivative 6. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：819 / 821

页数：3

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