New developments in chemistry of organometallic porphyrins and their analogs

被引：52
|
作者：
Vecchi, Andrea [1 ]
Galloni, Pierluca [1 ]
Floris, Barbara [1 ]
Nemykin, Victor N. [2 ]
机构：
[1] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, I-00133 Rome, Italy
[2] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA
来源：
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2013年 / 17卷 / 03期
基金：
美国国家科学基金会;
关键词：
organometallic porphyrins; synthesis; spectroscopy; redox properties; photoinduced electron-transfer; light-harvesting; FERROCENE-SUBSTITUTED PORPHYRIN; PHOTOINDUCED CHARGE SEPARATION; MIXED-VALENCE STATES; METAL-FREE; PERIPHERAL SUBSTITUENTS; ELECTRON-TRANSFER; ENERGY TRANSFERS; KEY ROLE; COMPLEXES; COMMUNICATION;
D O I：
10.1142/S1088424613300012
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this mini-review, new developments in chemistry of organometallic porphyrins and their analogs reported between 2007 and mid 2012 have been discussed. Synthetic strategies for preparation, as well as properties of metallocenyl-type compounds in which organometallic substituents connected to the porphyrinoid via (i) axial coordination; (ii) covalent bond to meso- or beta-pyrrolic position; or (iii) beta,beta'-fused into the aromatic system as well as porphyrinoids with organometallic fragments sigma-bonded in eta(1)-fashion were overviewed.
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页码：165 / 196
页数：32
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