New developments in chemistry of organometallic porphyrins and their analogs

被引：52

作者：

Vecchi, Andrea ^{[1
]}

Galloni, Pierluca ^{[1
]}

Floris, Barbara ^{[1
]}

Nemykin, Victor N. ^{[2
]}

机构：

[1] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, I-00133 Rome, Italy

[2] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2013年 / 17卷 / 03期

基金：

美国国家科学基金会;

关键词：

organometallic porphyrins; synthesis; spectroscopy; redox properties; photoinduced electron-transfer; light-harvesting; FERROCENE-SUBSTITUTED PORPHYRIN; PHOTOINDUCED CHARGE SEPARATION; MIXED-VALENCE STATES; METAL-FREE; PERIPHERAL SUBSTITUENTS; ELECTRON-TRANSFER; ENERGY TRANSFERS; KEY ROLE; COMPLEXES; COMMUNICATION;

D O I：

10.1142/S1088424613300012

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this mini-review, new developments in chemistry of organometallic porphyrins and their analogs reported between 2007 and mid 2012 have been discussed. Synthetic strategies for preparation, as well as properties of metallocenyl-type compounds in which organometallic substituents connected to the porphyrinoid via (i) axial coordination; (ii) covalent bond to meso- or beta-pyrrolic position; or (iii) beta,beta'-fused into the aromatic system as well as porphyrinoids with organometallic fragments sigma-bonded in eta(1)-fashion were overviewed.

引用

页码：165 / 196

页数：32

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