Raman Scattering of Internal Dynamics in Spinel Zn2TiO4 Nanostructures

被引:9
|
作者
Wongratanaphisan, D. [1 ,2 ]
Santhaveesuk, T. [2 ]
Choopun, S. [2 ]
机构
[1] Chiang Mai Univ, Fac Sci, Dept Phys & Mat Sci, Chiang Mai 50200, Thailand
[2] CHE, Thailand Ctr Excellence Phys, Bangkok 10400, Thailand
关键词
Thermal oxidation method; Raman scattering; spinel lattice; TIO2; ENHANCEMENT; ANATASE;
D O I
10.1080/10584587.2013.780149
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We present here the results of the Raman study of lattice dynamics and local compositional fluctuations in cubic spinel Zn2TiO4 nanostructures. The observed Raman modes of the spinel structure are identified and attributed to local vibrational modes. Additionally, the analysis of the nonpolar E-2(H) (approximate to 437cm(-1), 54.2 meV) and A(1g) (approximate to 716cm(-1), 88.7 meV) modes are made and contributed to lattice deformation associated with the distinct coordination preferences of Zn and Ti.
引用
收藏
页码:37 / 43
页数:7
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