Similarity approach to chemical reactivity. Torquoselectivity in pericyclic reactions

被引：2
|
作者：
Ponec, R [1 ]
Yuzhakov, G [1 ]
Pecka, J [1 ]
机构：
[1] CHARLES UNIV,DEPT ORGAN CHEM,PRAGUE 2,CZECH REPUBLIC
来源：
JOURNAL OF MATHEMATICAL CHEMISTRY | 1996年 / 20卷 / 3-4期
关键词：
D O I：
10.1007/BF01165350
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The recently proposed topological similarity index was applied to the elucidation of the interesting phenomenon of pericyclic reactivity, the so-called torquoselectivity. It has been shown that the similarity approach is indeed able to provide a simple and consistent explanation of this phenomenon even in nontrivial cases of counter-intuitive contrasteric control.
引用
收藏
页码：301 / 310
页数：10
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