Similarity approach to chemical reactivity. Torquoselectivity in pericyclic reactions

被引:2
|
作者
Ponec, R [1 ]
Yuzhakov, G [1 ]
Pecka, J [1 ]
机构
[1] CHARLES UNIV,DEPT ORGAN CHEM,PRAGUE 2,CZECH REPUBLIC
关键词
D O I
10.1007/BF01165350
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The recently proposed topological similarity index was applied to the elucidation of the interesting phenomenon of pericyclic reactivity, the so-called torquoselectivity. It has been shown that the similarity approach is indeed able to provide a simple and consistent explanation of this phenomenon even in nontrivial cases of counter-intuitive contrasteric control.
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页码:301 / 310
页数:10
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