Structure and magnetic property of Ru(II,III) dimer axially coordinated by the niroxide radical and water [Ru2(O2CCMe3)4(nitph)(H2O)]BF4, nitph=2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide

被引：11
|
作者：
Sayama, Y
Handa, M [1 ]
Mikuriya, M
Hiromitsu, I
Kasuga, K
机构：
[1] Kwansei Gakuin Univ, Sch Sci, Dept Chem, Nishinomiya, Hyogo 6628501, Japan
[2] Shimane Univ, Interdisciplinary Fac Sci & Engn, Dept Mat Sci, Matsue, Shimane 6908504, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2001年 / 74卷 / 11期
关键词：
D O I：
10.1246/bcsj.74.2129
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A ruthenium(II,III) pivalate dimer axially coordinated by a nitroxide radical and a water molecule, [Ru-2(O2CC-Me-3)(4)(nitph)(H2O)]BF4 (nitph = 2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide), has been prepared and characterized. The magnetic interaction between the Ru(II,III) core and the radical through the coordinated N-O group was estimated to be J = -45 cm(-1).
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收藏
页码：2129 / 2130
页数：2
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