Structure and magnetic property of Ru(II,III) dimer axially coordinated by the niroxide radical and water [Ru2(O2CCMe3)4(nitph)(H2O)]BF4, nitph=2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide

被引：11
|
作者：
Sayama, Y
Handa, M [1 ]
Mikuriya, M
Hiromitsu, I
Kasuga, K
机构：
[1] Kwansei Gakuin Univ, Sch Sci, Dept Chem, Nishinomiya, Hyogo 6628501, Japan
[2] Shimane Univ, Interdisciplinary Fac Sci & Engn, Dept Mat Sci, Matsue, Shimane 6908504, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2001年 / 74卷 / 11期
关键词：
D O I：
10.1246/bcsj.74.2129
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A ruthenium(II,III) pivalate dimer axially coordinated by a nitroxide radical and a water molecule, [Ru-2(O2CC-Me-3)(4)(nitph)(H2O)]BF4 (nitph = 2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide), has been prepared and characterized. The magnetic interaction between the Ru(II,III) core and the radical through the coordinated N-O group was estimated to be J = -45 cm(-1).
引用
收藏
页码：2129 / 2130
页数：2
相关论文
共 50 条
  • [21] Crystallography and magnetism of radicals with hindered hydroxyl groups:: 2-(3,5-di-tert-butyl-4-hydroxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole3-oxide-1-oxyl and 2-(3,5-di-tert-butyl-4-hydroxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl
    Taylor, P
    Lahti, PM
    CHEMICAL COMMUNICATIONS, 2004, (23) : 2686 - 2688
  • [22] catena-Poly[[diaquacobalt(II)]bis[μ-2-(4-carboxylatophenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 3-oxide]]
    Rong, Rong
    Gao, Ge
    Zhu, Lili
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M488 - U923
  • [23] 2-[1-(tert-Butoxycarbonyl)pyrrolidin-2-yl]-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide
    Jiang, Ru
    Wang, Hai-Bo
    Gao, Peng
    Jing, Lin-Lin
    Sun, Xiao-Li
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1954 - U649
  • [24] FORCE MICROSCOPY STUDIES OF LANGMUIR-BLODGETT-FILM OF 2-(4-(HEXADECYLOXY)PHENYL)-4,4,5,5-TETRAMETHYL-4,5-DIHYDRO-1H-IMIDAZOLYL-1-OXY-3-OXIDE
    BAI, CL
    ZHANG, PC
    ZHU, DB
    HAN, MY
    XU, Y
    ZHANG, DQ
    LIU, YQ
    JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (20): : 8202 - 8205
  • [25] Tetra(3-methoxypropionato)diruthenium(II,III) units:: Supramolecular organization in the complex [Ru2(μ-O2CCH2CH2OMe)4(H2O)2]BF4
    Barral, MC
    González-Prieto, R
    Jiménez-Aparicio, R
    Priego, JL
    Royer, EC
    Torres, MR
    Urbanos, FA
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (11): : 2075 - 2080
  • [26] Aquachlorobis[4,4,5,5-tetramethyl-2-(2-pyridyl)-4,5-dihydro-1H-imidazol-1-oxyl 3-oxide-κ2O1,N2]nickel(II) nitrate methanol disolvate monohydrate
    Lewis, GR
    Blake, AJ
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2002, 58 (07): : m398 - m400
  • [27] Electronic structure of the organic half-metallic magnet: 2-(5-pyrimidinyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-3-oxoimidazol-1-oxyl
    Wu, Ming-Hu
    Zou, Wei-Dong
    JOURNAL OF MATHEMATICAL CHEMISTRY, 2006, 40 (03) : 319 - 325
  • [28] Molecular and Crystal Structure of 2-Amino-Polyfluorophenyl-4,4,5,5-Tetramethyl-4,5-Dihydro-1H-Imidazol-3-Oxide-1-Oxyls
    Tretyakov, E. V.
    Makhneva, T. V.
    Politanskaya, L. V.
    Bagryanskaya, I. Yu.
    Stass, D. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (03) : 689 - 696
  • [29] Spin distribution and hydrogen-bond effect in ferromagnetic α-phase crystal of 2-(2′,5′-dihydroxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy-3-oxide
    Zhang, YS
    Yao, KL
    Liu, ZL
    Yu, LH
    Wang, XL
    JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (14):
  • [30] Crystal Packing and Magnetism in Phenolic Nitronylnitroxides: 2-(3′,5′-Dimethoxy-4′-hydroxyphenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl
    Seber, Gonca
    Freitas, Rafael S.
    Oliveira, Nei Fernandes, Jr.
    Lahti, Paul M.
    CRYSTAL GROWTH & DESIGN, 2013, 13 (02) : 893 - 900
12345