Structure and magnetic property of Ru(II,III) dimer axially coordinated by the niroxide radical and water [Ru2(O2CCMe3)4(nitph)(H2O)]BF4, nitph=2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide

被引：11

作者：

Sayama, Y

Handa, M ^{[1
]}

Mikuriya, M

Hiromitsu, I

Kasuga, K

机构：

[1] Kwansei Gakuin Univ, Sch Sci, Dept Chem, Nishinomiya, Hyogo 6628501, Japan

[2] Shimane Univ, Interdisciplinary Fac Sci & Engn, Dept Mat Sci, Matsue, Shimane 6908504, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2001年 / 74卷 / 11期

关键词：

D O I：

10.1246/bcsj.74.2129

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A ruthenium(II,III) pivalate dimer axially coordinated by a nitroxide radical and a water molecule, [Ru-2(O2CC-Me-3)(4)(nitph)(H2O)]BF4 (nitph = 2-phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide), has been prepared and characterized. The magnetic interaction between the Ru(II,III) core and the radical through the coordinated N-O group was estimated to be J = -45 cm(-1).

引用

页码：2129 / 2130

页数：2

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