Iron-catalyzed aerobic oxidative amidation of tertiary amines with carboxylic acids

被引：11
|
作者：
Ma, Lina [1 ]
Li, Yuanming [1 ]
Li, Zhiping [1 ]
机构：
[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
来源：
SCIENCE CHINA-CHEMISTRY | 2015年 / 58卷 / 08期
关键词：
amidation; tertiary amine; carboxylic acid; iron catalysis; oxidation; AMIDE BOND FORMATION; C-N BOND; 4-SUBSTITUTED N; N-DIALKYLANILINES; ATMOSPHERIC-PRESSURE; MOLECULAR-OXYGEN; ALCOHOLS; ALDEHYDES; CLEAVAGE; AMINOCARBONYLATION; DEALKYLATION;
D O I：
10.1007/s11426-015-5368-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An oxidative amidation of tertiary amines with carboxylic acids has been developed in the presence of FeCl3 center dot 6H(2)O as catalyst and oxygen as oxidant. A variety of tertiary amides were obtained in good to excellent yields from inexpensive and readily available reagents. The possible reaction pathways were investigated.
引用
收藏
页码：1310 / 1315
页数：6
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