Iron-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to α-olefins

被引：75
|
作者：
Maetani, Shinji [1 ]
Fukuyama, Takahide [1 ]
Suzuki, Nobuyoshi [2 ]
Ishihara, Daisuke [2 ]
Ryu, Ilhyong [1 ]
机构：
[1] Osaka Prefecture Univ, Dept Chem, Grad Sch Sci, Sakai, Osaka 5998531, Japan
[2] Kao Corp, Wakayama 6408580, Japan
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 19期
关键词：
CROSS-COUPLING REACTIONS; HYDROGEN-PEROXIDE; CARBON-MONOXIDE; ALKYL-HALIDES; COMPLEXES; OXIDATION; EFFICIENT; KETONES; EPOXIDATION; CONVERSION;
D O I：
10.1039/c2cc18093f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalytic decarbonylation reaction of aliphatic carboxylic acids can be carried out in the presence of an iron complex, and it proceeds smoothly to give alpha-olefins with high selectivity.
引用
收藏
页码：2552 / 2554
页数：3
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