Iron-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to α-olefins

被引：75
|
作者：
Maetani, Shinji [1 ]
Fukuyama, Takahide [1 ]
Suzuki, Nobuyoshi [2 ]
Ishihara, Daisuke [2 ]
Ryu, Ilhyong [1 ]
机构：
[1] Osaka Prefecture Univ, Dept Chem, Grad Sch Sci, Sakai, Osaka 5998531, Japan
[2] Kao Corp, Wakayama 6408580, Japan
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 19期
关键词：
CROSS-COUPLING REACTIONS; HYDROGEN-PEROXIDE; CARBON-MONOXIDE; ALKYL-HALIDES; COMPLEXES; OXIDATION; EFFICIENT; KETONES; EPOXIDATION; CONVERSION;
D O I：
10.1039/c2cc18093f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalytic decarbonylation reaction of aliphatic carboxylic acids can be carried out in the presence of an iron complex, and it proceeds smoothly to give alpha-olefins with high selectivity.
引用
收藏
页码：2552 / 2554
页数：3
相关论文
共 50 条
  • [21] Iron-Catalyzed Decarboxylative Alkyl Etherification of Vinylarenes with Aliphatic Acids as the Alkyl Source
    Jian, Wujun
    Ge, Liang
    Jiao, Yihang
    Qian, Bo
    Bao, Hongli
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (13) : 3650 - 3654
  • [22] Iron-Catalyzed Radical Annulation of Unsaturated Carboxylic Acids with Disulfides for the Synthesis of γ-Lactones
    Cheng, Fei
    Wang, Li-Li
    Mao, Yuan-Hu
    Dong, Yong-Xi
    Liu, Bin
    Zhu, Gao-Feng
    Yang, Yuan-Yong
    Guo, Bing
    Tang, Lei
    Zhang, Ji-Quan
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (13): : 8620 - 8629
  • [23] Iron-Catalyzed Reduction of Carboxylic Esters to Alcohols
    Junge, Kathrin
    Wendt, Bianca
    Zhou, Shaolin
    Beller, Matthias
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (11) : 2061 - 2065
  • [24] Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process
    Zhao, Jincan
    Fang, Hong
    Han, Jianlin
    Pan, Yi
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2013, 9 : 1718 - 1723
  • [25] Selective iron-catalyzed aerobic oxidation of alcohols in water to carboxylic acids mediated by additives
    Yu, Han
    Ren, Jingjing
    Xie, Ya
    Su, Xiaofang
    Wang, Aiping
    Yan, Likai
    Jiang, Feng
    Wei, Yongge
    GREEN CHEMISTRY, 2022, 24 (17) : 6511 - 6516
  • [26] Iron-catalyzed Selective Oxidation of α,β-Unsaturated Aldehydes to α,β-Unsaturated Carboxylic Acids by Molecular Oxygen
    Tanaka, Shinji
    Kon, Yoshihiro
    Uesaka, Yumiko
    Morioka, Ryo
    Tamura, Masanori
    Sato, Kazuhiko
    CHEMISTRY LETTERS, 2016, 45 (02) : 188 - 190
  • [27] Cationic iron-catalyzed intramolecular hydroalkoxylation of unactivated olefins
    Komeyama, Kimihiro
    Morimoto, Takayuki
    Nakayama, Yuushou
    Takaki, Ken
    TETRAHEDRON LETTERS, 2007, 48 (18) : 3259 - 3261
  • [28] Iron-catalyzed epoxidation of olefins using hydrogen peroxide
    Hasan, Kamrul
    Brown, Nicole
    Kozak, Christopher M.
    GREEN CHEMISTRY, 2011, 13 (05) : 1230 - 1237
  • [29] Iron-Catalyzed Epoxidation of Linear α-Olefins with Hydrogen Peroxide
    Mao, Shuxin
    Budweg, Svenja
    Spannenberg, Anke
    Wen, Xiaodong
    Yang, Yong
    Li, Yong-Wang
    Junge, Kathrin
    Beller, Matthias
    CHEMCATCHEM, 2022, 14 (04)
  • [30] Iron-Catalyzed Direct Diazidation for a Broad Range of Olefins
    Yuan, Yong-An
    Lu, Deng-Fu
    Chen, Yun-Rong
    Xu, Hao
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (02) : 534 - 538
12345