The effect of the partial pressure of H2 gas and atomic hydrogen on diamond films deposited using CH30H/H2O gas

被引:0
|
作者
Lee, KJ [1 ]
Koh, JG
Shin, JS
Kwon, KH
机构
[1] Soongsil Univ, Dept Phys, Seoul 156013, South Korea
[2] Daejeon Univ, Dept Adv Mat Engn, Taejon 300716, South Korea
[3] Hyejeon Coll, Dept Ind Engn, Hongsung 350702, South Korea
关键词
HFCVD; CH3OH/H2O gas; diamond; OES; H-alpha; H-beta; H-gamma;
D O I
暂无
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Diamond films were deposited on Si(100) substrates by hot filament chemical vapor deposition (HFCVD) with a CH3OH/H2O gas mixture while changing the gas ratio. The films were analyzed with scanning electron microscopy (SEM), Raman spectroscopy, and optical emission spectroscopy (OES). The diamond films were grown with CH3OH being 52% by volume of the gas mixture. The effect of atomic hydrogen on the film was different from that of the CH4/H-2 gas mixture. Analysis with OES during film growth indicated that among the thermally dissociated hydrogen radicals, only H. contributed to the etching of graphite.
引用
收藏
页码:141 / 145
页数:5
相关论文
共 50 条
  • [31] Toward smooth MWPECVD diamond films: Exploring the limits of the hydrogen percentage in Ar/H2/CH4 gas mixture
    Cicala, G.
    Moneger, D.
    Cornacchia, D.
    Pesce, P.
    Magaletti, V.
    Perna, G.
    Capozzi, V.
    Tamborra, M.
    SURFACE & COATINGS TECHNOLOGY, 2012, 211 : 152 - 157
  • [32] Interaction Energy and the Shift in OH Stretch Frequency on Hydrogen Bonding for the H2O→H2O, CH3OH→H2O, and H2O→CH3OH dimers
    Campen, Richard Kramer
    Kubicki, James D.
    JOURNAL OF COMPUTATIONAL CHEMISTRY, 2010, 31 (05) : 963 - 972
  • [33] Theoretical calculations of pressure broadening coefficients for H2O perturbed by hydrogen or helium gas
    Gamache, RR
    Lynch, R
    Brown, LR
    JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 1996, 56 (04): : 471 - 487
  • [34] Gas hydrate formation in the system C2H6–H2–H2O at pressures up to 250 MPa
    Sergey S. Skiba
    Eduard G. Larionov
    Andrey Yu. Manakov
    Sergey I. Kozhemjachenko
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2010, 67 : 353 - 359
  • [35] THE CORROSION BEHAVIOR OF NI-MO ALLOYS IN A H2/H2O/H2S GAS-MIXTURE
    HE, YR
    DOUGLASS, DL
    GESMUNDO, F
    OXIDATION OF METALS, 1992, 37 (5-6): : 413 - 439
  • [36] Effect of pressure on nanocrystalline diamond films deposition by hot filament CVD technique from CH4/H2/Ar gas mixture
    Yang, Shumin
    He, Zhoutong
    Zhu, Dezhang
    Gong, Jinlong
    2008 2ND IEEE INTERNATIONAL NANOELECTRONICS CONFERENCE, VOLS 1-3, 2008, : 928 - 930
  • [37] HIGH-PRECISION D/H MEASUREMENTS FROM H2 GAS AND H2O BY CONTINUOUS-FLOW IRMS
    TOBIAS, HJ
    GOODMAN, KJ
    BLACKEN, CE
    BRENNA, JT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 42 - GEOC
  • [38] Gas-jet synthesis of diamond-like films from an H2 + CH4 gas mixture glow
    Emel'yanov, A. A.
    Rebrov, A. K.
    Yudin, I. B.
    JOURNAL OF APPLIED MECHANICS AND TECHNICAL PHYSICS, 2014, 55 (02) : 270 - 275
  • [39] Gas-jet synthesis of diamond-like films from an H2 + CH4 gas mixture glow
    A. A. Emel’yanov
    A. K. Rebrov
    I. B. Yudin
    Journal of Applied Mechanics and Technical Physics, 2014, 55 : 270 - 275
  • [40] Study of the ν1 band shape of the H2O ••• HF, H2O ••• DF, and H2O ••• HCl complexes in the gas phase
    Bulychev, VP
    Grigoriev, IM
    Gromova, EI
    Tokhadze, KG
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2005, 7 (11) : 2266 - 2278