Electrochemical fluorination of fullerene C-60 using a fluoride ion conductor PbSnF4

被引：0
|
作者：
Matsuo, Y
Sugie, Y
机构：
来源：
PROCEEDINGS OF THE SYMPOSIUM ON ELECTROCHEMISTRY IN THE PREPARATION OF FLUORINE AND ITS COMPOUNDS | 1997年 / 97卷 / 15期
关键词：
D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Fullerene C-60 has been fluorinated by a new electrochemical method using a fluoride ion conductor PbSnF4 which is used as an electrolyte and a separator between cathode and anode compartments. When C-60 was fluorinated by a potentiostatic method, abrupt increase of the current was observed after about 6-20 hours induction time. The absorption peaks at 1040cm(-1) and 1080cm(-1) derived of tertiary C-F bond were observed in IR spectra of C-60 samples fluorinated below 2.0V vs Cu/CuF2 in benzene, while those fluorinated at 3.0V in benzene or at 1.9V in 1,1,2,2-tetrachloroethane showed absorption peaks at around 1250cm(-1) due to -CF3 or >CF2 which would be formed as the result of the destruction of the cage structure of C-60.
引用
收藏
页码：213 / 219
页数：7
相关论文
共 50 条
  • [31] INTERCALATION OF THE FECL4 ION IN C-60/C-70 - MAGNETIC-PROPERTIES OF THE RESULTING COMPOUND
    KSARI, Y
    CHOUTEAU, G
    YAZAMI, R
    CHERIGUI, A
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1995, 140 : 2061 - 2062
  • [32] Interaction of tetrasubstituted dihalcogenapyranylidenes with fullerene and molecular complex of fullerene with tetraphenyldipyranylidene (C-60)(2)center dot TPDP center dot(CS2)(4)
    Konarev, DV
    Roschupkina, OS
    Kaplunov, MG
    Shulga, YM
    Yudanova, EI
    Lyubovskaya, RN
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION C-MOLECULAR MATERIALS, 1996, 8 (1-2): : 83 - 86
  • [33] Electrochemical STM investigation of C70, C60/C70 mixed fullerene and hydrogenated fullerene adlayers on Au(111) prepared using the electrochemical replacement method
    Uemura, Shinobu
    Taniguchi, Isao
    Sakata, Masayo
    Kunitake, Masashi
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2008, 623 (01) : 1 - 7
  • [34] Comparative Study of Vibrational Spectra of Fullerene C-60, C-70, C-80 and C-84 using U(2) Lie Algebra
    Sen, Rupam
    Kalyan, Ashim
    Das, Raghunandan
    Choudhury, Joydeep
    Sarkar, Nirmal Kumar
    Bhattacharjee, Ramendu
    AFRICAN REVIEW OF PHYSICS, 2011, 6
  • [35] Electrochemical investigations of prednisone using fullerene-C60-modified edge plane pyrolytic graphite electrode
    Goyal, Rajendra N.
    Singh, Sudhanshu P.
    Chatterjee, Sanghamitra
    Bishnoi, Sunita
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2010, 49 (01): : 26 - 33
  • [36] Synthesis of calix[4,5,6] resorcinarenes using fullerene C60 as template
    Klimova, T
    Klimova, E
    Vázquez, RA
    Gutierrez, NM
    Martínez, M
    FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2003, 11 (03) : 269 - 281
  • [37] Low-dimensional Li plus ion dynamics in the lithiated Buckminster fullerene Li4C60
    Gadermaier, Bernhard
    Wilkening, H. Martin R.
    SOLID STATE IONICS, 2025, 421
  • [38] SELECTED-ION FLOW TUBE STUDY OF CHARGE-TRANSFER FROM FULLERENE DICATIONS - BRACKETING THE 2ND-IONIZATION ENERGIES OF C-60 AND C-70
    PETRIE, S
    JAVAHERY, G
    WANG, JR
    BOHME, DK
    JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (15): : 6121 - 6123
  • [39] Asymmetric fission and evaporation of C60r+ (r=2-4) fullerene ions in ion-C60 collisions:: I.: Proton results
    Rentenier, A
    Bordenave-Montesquieu, A
    Moretto-Capelle, P
    Bordenave-Montesquieu, D
    JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2004, 37 (12) : 2429 - 2454
  • [40] DETERMINATION OF THE C-70 C-60 RATIO IN FULLERENE THIN-FILMS AS A FUNCTION OF THE SUBLIMATION DISTANCE AND THE SUBSTRATE-TEMPERATURE USING SCANNING-TUNNELING-MICROSCOPY
    LANG, HP
    HEEGER, KM
    THOMMENGEISER, V
    GUNTHERODT, HJ
    PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1994, 70 (03): : 721 - 730
12345