Electrochemical fluorination of fullerene C-60 using a fluoride ion conductor PbSnF4

被引：0
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作者：
Matsuo, Y
Sugie, Y
机构：
来源：
PROCEEDINGS OF THE SYMPOSIUM ON ELECTROCHEMISTRY IN THE PREPARATION OF FLUORINE AND ITS COMPOUNDS | 1997年 / 97卷 / 15期
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中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Fullerene C-60 has been fluorinated by a new electrochemical method using a fluoride ion conductor PbSnF4 which is used as an electrolyte and a separator between cathode and anode compartments. When C-60 was fluorinated by a potentiostatic method, abrupt increase of the current was observed after about 6-20 hours induction time. The absorption peaks at 1040cm(-1) and 1080cm(-1) derived of tertiary C-F bond were observed in IR spectra of C-60 samples fluorinated below 2.0V vs Cu/CuF2 in benzene, while those fluorinated at 3.0V in benzene or at 1.9V in 1,1,2,2-tetrachloroethane showed absorption peaks at around 1250cm(-1) due to -CF3 or >CF2 which would be formed as the result of the destruction of the cage structure of C-60.
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页码：213 / 219
页数：7
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