Highly Regioselective Hydroformylation of Styrene and Its Derivatives Catalyzed by Rh Complex with Tetraphosphorus Ligands

被引：65
|
作者：
Yu, Shichao
Chie, Yu-ming
Guan, Zheng-hui
Zou, Yaping
Li, Wei
Zhang, Xumu [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 01期
关键词：
ASYMMETRIC HYDROFORMYLATION; ENANTIOSELECTIVE HYDROFORMYLATION; ISOMERIZATION-HYDROFORMYLATION; CARBOXYLIC-ACIDS; INTERNAL OLEFINS; IN-SITU; ALDEHYDES; REDUCTION; OXIDATION; CHLORIDES;
D O I：
10.1021/ol802479y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Styrene has been hydroformylated to the linear aldehyde with surprisingly high regioselectivity (1/b up to 22 for styrene) by using Rh complex with tetraphosphorus ligand. To the best of our knowledge, this is the highest linear regioselectivity reported for the hydroformylation of styrene and Its derivatives. This protocol Is In sharp contrast to other processes that favor producing branched aldehyde (typically > 95% branched for most bidentate systems).
引用
收藏
页码：241 / 244
页数：4
相关论文
共 50 条
  • [21] Rhodium-catalyzed regioselective hydroaminomethylation of terminal olefins with pyrrole-based tetraphosphorus ligands
    Liu, Guodu
    Li, Zhao
    Geng, Huiling
    Zhang, Xumu
    CATALYSIS SCIENCE & TECHNOLOGY, 2014, 4 (04) : 917 - 921
  • [22] Hydroformylation and acetalization of styrene derivatives catalyzed by Rh(III)-phosphite and Rh(III) supported on MCM-41-phosphite systems.
    El Ali, B
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U252 - U252
  • [23] Rh, Co, Ru and Pd complex catalyzed hydroformylation of ethylene using triphenylphosphine, triphenylarsine and triphenylstibine as ligands
    Srivastava, VK
    Bhatt, SD
    Shukla, RS
    Bajaj, HC
    Jasra, RV
    REACTION KINETICS AND CATALYSIS LETTERS, 2005, 85 (01): : 3 - 9
  • [24] Rh, Co, Ru and Pd complex catalyzed hydroformylation of ethylene using triphenylphosphine, triphenylarsine and triphenylstibine as ligands
    Vivek K. Srivastava
    Sharad D. Bhatt
    Ram S. Shukla
    Hari C. Bajaj
    Raksh V .Jasra
    Reaction Kinetics and Catalysis Letters, 2005, 85 : 3 - 9
  • [25] Probing new classes of π-acceptor ligands for rhodium catalyzed hydroformylation of styrene
    Breit, B
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 143 (1-3) : 143 - 154
  • [26] Highly regioselective hydroformylation of 1-dodecene catalyzed by Rh-BISBIS in aqueous two-phase system
    Chen, H
    Li, YZ
    Li, RX
    Cheng, PM
    Li, XJ
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 198 (1-2) : 1 - 7
  • [27] Rh-catalyzed asymmetric hydroformylation of olefins using phosphorus ligands
    Kumar, Rohit
    Sen, Anirban
    Chikkali, Samir H.
    JOURNAL OF CHEMICAL SCIENCES, 2023, 135 (04)
  • [28] Development and applications of phosphorus ligands in Rh-catalyzed hydroformylation reactions
    Cao, Bonan
    Zhang, Xiaowei
    Cai, Chaoxian
    Yu, Shichao
    Yan, Yongjun
    Hu, Xinquan
    Zhang, Xumu
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [29] Modular Synthesis of Phosphite and Phosphoramidite Ligands for Rh-Catalyzed Hydroformylation
    Li, Changjiang
    Li, Zhaozhou
    Tan, Kunpeng
    Liu, Guodu
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 26 (33)
  • [30] Rh-catalyzed asymmetric hydroformylation of olefins using phosphorus ligands
    Rohit Kumar
    Anirban Sen
    Samir H Chikkali
    Journal of Chemical Sciences, 135
12345