Rh, Co, Ru and Pd complex catalyzed hydroformylation of ethylene using triphenylphosphine, triphenylarsine and triphenylstibine as ligands

被引：6
|
作者：
Srivastava, VK [1 ]
Bhatt, SD [1 ]
Shukla, RS [1 ]
Bajaj, HC [1 ]
Jasra, RV [1 ]
机构：
[1] Cent Salt & Marine Chem Res Inst, Silicates & Catalysis Discipline, Bhavnagar 364002, Gujarat, India
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2005年 / 85卷 / 01期
关键词：
hydroformylation; ethylene; catalysis; co; ru; rh; pd; PPh3; AsPh3; SbPh3;
D O I：
10.1007/s11144-005-0236-z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic activities of the complexes of Pd, Ru, Co, and Rh with PPh3, AsPh3 and SbPh3 ligands have been investigated for the hydroformylation of ethylene in benzene as solvent. All the studied metal complexes, other than that of Rh, with AsPh3 ligand were found to show better hydroformylation catalytic activity than those of their corresponding complexes with PPh3 and SbPh3 ligands.
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页码：3 / 9
页数：7
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