Highly Regioselective Hydroformylation of Styrene and Its Derivatives Catalyzed by Rh Complex with Tetraphosphorus Ligands

被引：65
|
作者：
Yu, Shichao
Chie, Yu-ming
Guan, Zheng-hui
Zou, Yaping
Li, Wei
Zhang, Xumu [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 01期
关键词：
ASYMMETRIC HYDROFORMYLATION; ENANTIOSELECTIVE HYDROFORMYLATION; ISOMERIZATION-HYDROFORMYLATION; CARBOXYLIC-ACIDS; INTERNAL OLEFINS; IN-SITU; ALDEHYDES; REDUCTION; OXIDATION; CHLORIDES;
D O I：
10.1021/ol802479y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Styrene has been hydroformylated to the linear aldehyde with surprisingly high regioselectivity (1/b up to 22 for styrene) by using Rh complex with tetraphosphorus ligand. To the best of our knowledge, this is the highest linear regioselectivity reported for the hydroformylation of styrene and Its derivatives. This protocol Is In sharp contrast to other processes that favor producing branched aldehyde (typically > 95% branched for most bidentate systems).
引用
收藏
页码：241 / 244
页数：4
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