Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)-naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers

被引：254

作者：

Wang, Huadong ^{[1
]}

Froehlich, Roland ^{[1
]}

Kehr, Gerald ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 45期

关键词：

D O I：

10.1039/b813286k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The "frustrated Lewis pair'' 1,8-bis(diphenylphosphino)-naphthalene/B(C6F5)(3) reversibly activates dihydrogen; it serves as an active catalyst for the hydrogenation of silyl enol ethers under mild reaction conditions.

引用

页码：5966 / 5968

页数：3