Heterolytic dihydrogen activation with the 1,8-bis(diphenylphosphino)-naphthalene/B(C6F5)3 pair and its application for metal-free catalytic hydrogenation of silyl enol ethers

被引：254
|
作者：
Wang, Huadong [1 ]
Froehlich, Roland [1 ]
Kehr, Gerald [1 ]
Erker, Gerhard [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 45期
关键词：
D O I：
10.1039/b813286k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The "frustrated Lewis pair'' 1,8-bis(diphenylphosphino)-naphthalene/B(C6F5)(3) reversibly activates dihydrogen; it serves as an active catalyst for the hydrogenation of silyl enol ethers under mild reaction conditions.
引用
收藏
页码：5966 / 5968
页数：3
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