Electrochemical behavior and voltammetric determination of ammonium dinitramide using a graphene film modified glassy carbon electrode

被引:10
|
作者
Najafi, Mostafa [1 ]
Darabi, Salman [1 ]
机构
[1] Imam Hossein Univ, Dept Chem, Fac Sci, Tehran 16597, Iran
关键词
Ammonium dinitramide; Grapheme; Modified electrode; Electrocatalysis; Electrochemical behavior; ADN; DECOMPOSITION; PLATFORM;
D O I
10.1016/j.electacta.2013.12.145
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A graphene modified glassy carbon electrode (GMGCE) was developed to investigate the electroreduction of ammonium dinitramide (ADN) using cyclic voltammetry and differential pulse voltammetry techniques. ADN was reduced with higher rates at low potentials on GMGCE compared to GCE. The GMGCE exhibited fast response towards ADN with a detection limit of 2.0 x 10(-6) M and a linear range of 2.5 x 10(-6) to 8.5 x 10(-4) M. The possible interference from several common ions was tested. The proposed method was successfully applied in the determination of ADN in water samples. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:315 / 320
页数:6
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