Design and synthesis of metal-carboxylate frameworks with permanent microporosity

被引：78
|
作者：
Eddaoudi, M
Li, HL
Reineke, T
Fehr, M
Kelley, D
Groy, TL
Yaghi, OM
机构：
[1] Arizona State Univ, Dept Chem & Biochem, Supramol Design & Discovery Grp, Tempe, AZ 85287 USA
[2] Nalco Chem Co, Naperville, IL 60563 USA
来源：
TOPICS IN CATALYSIS | 1999年 / 9卷 / 1-2期
关键词：
metal-organic; microporous; frameworks; sorption; isotherm;
D O I：
10.1023/A:1019110622091
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Metal-carboxylate clusters are ideally suited as secondary building units (SBU) for the assembly of extended open frameworks. Examples extracted from the chemistry of the multidentate building block 1,4-benzenedicarboxylate (BDC) show that Zn(BDC) clusters lead to the formation of rigid, stable and truly microporous metal-carboxylate networks. Gas sorption isotherms measured for this class of materials show type (I) gas uptake that is analogous to those observed for zeolites and molecular sieves.
引用
收藏
页码：105 / 111
页数：7
相关论文
共 50 条
  • [41] Porous Anionic, Cationic, and Neutral Metal-Carboxylate Frameworks Constructed from Flexible Tetrapodal Ligands: Syntheses, Structures, Ion-Exchanges, and Magnetic Properties
    Liu, Tian-Fu
    Lue, Jian
    Tian, Chongbin
    Cao, Minna
    Lin, Zujin
    Cao, Rong
    INORGANIC CHEMISTRY, 2011, 50 (06) : 2264 - 2271
  • [42] POROSITY ENHANCEMENT DURING CLASTIC DIAGENESIS AS A RESULT OF AQUEOUS METAL-CARBOXYLATE COMPLEXATION - EXPERIMENTAL STUDIES
    FEIN, JB
    CHEMICAL GEOLOGY, 1994, 115 (3-4) : 263 - 279
  • [43] Design and Synthesis of Zwitterionic Metal-Organic Frameworks
    Brockett, Jenna
    Alomari, Shefa
    Wriedt, Mario
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2018, 74 : A460 - A460
  • [44] A DFT/CDM study of metal-carboxylate interactions in metalloproteins: Factors governing the maximum number of metal-bound carboxylates
    Dudevt, Todor
    Lim, Carmay
    Journal of the American Chemical Society, 1600, 128 (05): : 1553 - 1561
  • [45] Viscoelastic and Dielectric Behavior of Polyisoprene Monofunctionally Head-Modified with Associative Metal-Carboxylate Group
    Matsumiya, Yumi
    Watanabe, Hiroshi
    Sukhonthamethirat, Natchamon
    Vao-soongnern, Visit
    NIHON REOROJI GAKKAISHI, 2021, 49 (03) : 189 - 197
  • [46] A DFT/CDM study of metal-carboxylate interactions in metalloproteins: Factors governing the maximum number of metal-bound carboxylates
    Dudev, T
    Lim, C
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (05) : 1553 - 1561
  • [47] Europium metal-organic framework containing helical metal-carboxylate chains for fluorescence sensing of nitrobenzene and nitrofunans antibiotics
    Sun, Shuang-Li
    Sun, Xi-Yu
    Sun, Qian
    Gao, En-Qing
    Zhang, Juan-Li
    Li, Wei-Jia
    JOURNAL OF SOLID STATE CHEMISTRY, 2020, 292
  • [48] One-Step Room-Temperature Synthesis of Metal(IV) Carboxylate Metal-Organic Frameworks
    Dai, Shan
    Nouar, Farid
    Zhang, Sanjun
    Tissot, Antoine
    Serre, Christian
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (08) : 4282 - 4288
  • [49] Synthesis and Characterization of Zn-Carboxylate Metal-Organic Frameworks Containing Triazatruxene Ligands
    Alkas, Adil
    Telfer, Shane G.
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2019, 72 (10) : 786 - 796
  • [50] A New Interpenetrated Metal-Carboxylate Zn(II) Complex: for Inhibiting Growth of Human Cervical Cancer Cells
    Gao, Jiayin
    Mao, Min
    Wang, Beidi
    Li, Peiling
    LATIN AMERICAN JOURNAL OF PHARMACY, 2016, 35 (05): : 1033 - 1036
12345