Design and synthesis of metal-carboxylate frameworks with permanent microporosity

被引：78
|
作者：
Eddaoudi, M
Li, HL
Reineke, T
Fehr, M
Kelley, D
Groy, TL
Yaghi, OM
机构：
[1] Arizona State Univ, Dept Chem & Biochem, Supramol Design & Discovery Grp, Tempe, AZ 85287 USA
[2] Nalco Chem Co, Naperville, IL 60563 USA
来源：
TOPICS IN CATALYSIS | 1999年 / 9卷 / 1-2期
关键词：
metal-organic; microporous; frameworks; sorption; isotherm;
D O I：
10.1023/A:1019110622091
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Metal-carboxylate clusters are ideally suited as secondary building units (SBU) for the assembly of extended open frameworks. Examples extracted from the chemistry of the multidentate building block 1,4-benzenedicarboxylate (BDC) show that Zn(BDC) clusters lead to the formation of rigid, stable and truly microporous metal-carboxylate networks. Gas sorption isotherms measured for this class of materials show type (I) gas uptake that is analogous to those observed for zeolites and molecular sieves.
引用
收藏
页码：105 / 111
页数：7
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