Regioselective hydroxylactonization of γ,δ-unsaturated carboxylic acids with hydrogen peroxide catalyzed by methyltrioxorhenium

被引：16

作者：

Tan, HS

Espenson, JH ^{[1
]}

机构：

[1] Iowa State Univ Sci & Technol, Ames Lab, Ames, IA 50011 USA

[2] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 142卷 / 03期

关键词：

catalysis; rhenium; peroxide; lactonization;

D O I：

10.1016/S1381-1169(98)00307-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of unsaturated carboxylic acids and esters to lactones with hydrogen peroxide is catalyzed by methyltrioxorhenium (MTO). The reaction proceeds regioselectively in high yield. On the basis of the results of this investigation and a comparison with previous work, a concerted process and mechanism have been suggested. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：333 / 338

页数：6

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