Self-assembly of halogen adducts of ester and carboxylic acid functionalised 1,3-dithiole-2-thiones

被引：9

作者：

Skabara, PJ

Berridge, R

Bricklebank, N

Lath, H

Coles, SJ

Horton, PN

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Sheffield Hallam Univ, Ctr Biomed Res, Sheffield S1 1WB, S Yorkshire, England

[3] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

POLYHEDRON | 2006年 / 25卷 / 04期

关键词：

dihalogen adducts; supramolecular chemistry; X-ray crystallography;

D O I：

10.1016/j.poly.2005.11.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New halogen adducts of 1,3-dithiole-2-thione-4-carboxylic acid and dimethyl 1,3-dithiole-2-thione-4,5-dicarboxylate have been prepared and characterised by X-ray crystallographic studies. The adducts feature an array of intramolecular and intermolecular close contacts involving chalcogen-chalcogen, chalcogen-halogen and halogen-halogen interactions. Whilst these contacts are derived from the basic heterocyclic unit and the coordinated halogen molecules, the ester and acid functionalities provide a varied and rich array of hydrogen bonding motifs, which significantly enhance the long-range order of the supramolecular structures. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：989 / 995

页数：7

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