We investigate numerically using the bond-fluctuation model the adsorption of a random AB copolymer at the interface between two solvents. From our results we infer several scaling relations: the radius of gyration of the copolymer in the direction perpendicular to the interface (R(gz)) scales with chi, the interfacial selectivity strength, as R(gz)=N(nu)f(root N chi) where nu is the usual Flory exponent and N is the copolymer's length; furthermore the monomer density at the interface scales as chi(2 nu) for Small chi. We also determine numerically the monomer densities in the two solvents and discuss their dependence on the distance from the interface.
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Department of Physics, University of California, Santa Criiz, CA. 95064, United StatesDepartment of Physics, University of California, Santa Criiz, CA. 95064, United States
Barber, W.C.
Belanger, D.P.
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Department of Physics, University of California, Santa Criiz, CA. 95064, United StatesDepartment of Physics, University of California, Santa Criiz, CA. 95064, United States
机构:
Adam Mickiewicz Univ Poznan, Fac Phys, PL-61614 Poznan, PolandAdam Mickiewicz Univ Poznan, Fac Phys, PL-61614 Poznan, Poland
Knychala, P.
Banaszak, M.
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Adam Mickiewicz Univ Poznan, Fac Phys, PL-61614 Poznan, PolandAdam Mickiewicz Univ Poznan, Fac Phys, PL-61614 Poznan, Poland
Banaszak, M.
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Park, M. J.
Balsara, N. P.
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Univ Calif Berkeley, Dept Chem Engn, Div Mat Sci, Berkeley, CA 94720 USA
Univ Calif Berkeley, Lawrence Berkeley Lab, Environm Energy Technol Div, Berkeley, CA 94720 USAAdam Mickiewicz Univ Poznan, Fac Phys, PL-61614 Poznan, Poland