Monte Carlo simulations of random copolymers at a selective interface

被引:19
|
作者
Peng, GW [1 ]
Sommer, JU [1 ]
Blumen, A [1 ]
机构
[1] ACAD SINICA,INST PHYS,BEIJING 100080,PEOPLES R CHINA
来源
PHYSICAL REVIEW E | 1996年 / 53卷 / 05期
关键词
D O I
10.1103/PhysRevE.53.5509
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We investigate numerically using the bond-fluctuation model the adsorption of a random AB copolymer at the interface between two solvents. From our results we infer several scaling relations: the radius of gyration of the copolymer in the direction perpendicular to the interface (R(gz)) scales with chi, the interfacial selectivity strength, as R(gz)=N(nu)f(root N chi) where nu is the usual Flory exponent and N is the copolymer's length; furthermore the monomer density at the interface scales as chi(2 nu) for Small chi. We also determine numerically the monomer densities in the two solvents and discuss their dependence on the distance from the interface.
引用
收藏
页码:5509 / 5512
页数:4
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