Metal-organic frameworks as catalysts: the role of metal active sites

被引：281

作者：

Valvekens, Pieterjan ^{[1
]}

Vermoortele, Frederik ^{[1
]}

De Vos, Dirk ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 06期

关键词：

MOLECULAR-SIEVES; MESOPOROUS ORGANOSILICAS; HETEROGENEOUS CATALYSIS; OXIDATION; MOFS; CONVERSION; VANADIUM; COMBINATION; COMPLEXES; FTIR;

D O I：

10.1039/c3cy20813c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this perspective we first critically compare the use of metal-organic frameworks (MOFs) as supports for catalytic functions with the possibilities offered by other classes of porous materials. We then discuss the incidental or deliberate formation of active sites in MOF lattices, and review some strategies to control the number and activity of these sites, ultimately resulting in MOF catalysts with improved performance.

引用

页码：1435 / 1445

页数：11

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